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期刊论文
Reactions of N-sulfenyl-1,2-benzisothiazolin-3-ones with nucleophiles
Tetrahedron 60(2004)11359-11366,-0001,():
Reactions of N-[2-(alkoxycarbonyl)benzenesulfenyl]-1,2-benzisothiazolin-3-ones (1) with various nucleophiles were examined. Anions of active methylene compounds attacked the sulfur atoms of the sulfenyl moieties of 1 to afford sulfide compounds, while thiols attacked the sulfur atoms of the benzisothiazolinone moieties of 1 to afford ring-opened products. Grignard reagents attacked both the above sulfur atoms to give ring-opened products along with sulfide compounds.
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