This paper comparatively analyzes the existing evaluation index of websites, and puts forward the evaluation index and method about the support of a website to enterprise's e-commerce. Through researching on 56 super enterprises of information industry in Sichuan province, throughout China and the world, analyzing and comparatively studying the support ability of a website to an enterprise's e-commerce, this paper brings forward using five levels to categorize the support ability of a website to enterprise's e-commerce. In the end, the flaw of enterprise's e-commerce practice in Sichuan province and corresponding countermeasure will be illustrated.