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期刊论文

Solubilities of benzene and diphenyl in (t-butyl alcohol Hwater) and hydrophobic interaction

邹立壮Lizhuang Zoua Buxing Han Ruilin Liu and Haike Yan b

J. Chem. Thermodynamics 1997, 29, 1289-1299,-0001,():

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摘要/描述

The solubilities of benzene and diphenyl in mixed solvents of t-butyl alcohol TBA. and water at Ts298.15, 303.15, 308.15, and 313.15. K have been determined by spectrophotometry. The mole fractions of TBA in the mixed solvent are xs0, 0.010, 0.020, 0.030, 0.040, 0.045, 0.050, 0.060, 0.080, and 0.150., respectively. The standard Gibbs energies of solution of benzene and diphenyl have been calculated based on the solubility data. The hydrophobic interaction HI. for the pair benzene]benzene in the mixed solvent has also been calculated and discussed.

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