熔体反应合成Al-(Mg)-C合金
首发时间:2004-06-17
摘要:碳与铝液的润湿性差,在铝液中的溶解度低,很难将碳直接加入纯铝或铝合金液,同时已经发现碳和铝共同加入镁合金可起到高效的细化晶粒作用,因此,研究Al-C反应,合成Al-C合金具有重要的意义。本文采用熔体反应,即将石墨粉直接加入纯铝或Al-Mg合金熔体反应3-10分钟的工艺方法成功合成了Al-Mg-C和 Al-C合金。在800-900℃制备的Al-Mg-C合金中碳主要以单质的形式存在,在1100-1200℃制备的Al-C和Al-Mg-C合金中碳绝大部分与铝反应生成了Al4C3化合物。Al4C3在铝合金基体中的生成大大降低了铝熔体的流动性。空气中的水汽很容易侵入Al-C合金基体内部与Al4C3反应。
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Synthesis of Al-(Mg)-C alloys in molten Al
Abstract:ecause of the poor wettability and especially low solubility of carbon in Al melt, it is difficult to add carbon directly into molten Al alloy to produce such carbides as TiC, ZrC,etc in the matrix; It has been found that simultaneous addition of Al and carbon into Mg alloy can cause excellent grain refinement effect. Thus, study of the Al-C reaction and synthesis of Al-C alloys is of great interest and importance. In this paper, Al-Mg-C and Al-C alloys have been successfully produced through melt reaction approach, i.e. direct adding graphite powder into molten Al-Mg or pure Al followed by 3-10minutes of reaction. Graphite in the Al-Mg-C alloy produced between 800-900℃ mainly exist in the form of pure element carbon, while the form of Al4C3 in the Al-Mg-C or Al-C alloys produced in the temperature range of 1100-1200℃.The formation of Al4C3 compound in the Al-C and Al-Mg-C alloys greatly decreases the fluidity of the melt. The moisture in the air readily invades into the bulk body of
Keywords: Melt reaction Al-C alloy Al4C3, Grain refinement
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