The sp-hybrid Bonding of C, N and O to the fcc(001) Surface of Nickel and Rhodium
首发时间:2005-07-07
Abstract:A brief review is given focusing on the nature, kinetics, dynamics and consequences of the sp-orbital hybrid bonding of C, N and O to the Ni/Rh(001) surfaces which give rise to the same kind of "radial and then the p4g clock" reconstruction . It is identified that the "radial" and the subsequent "clock" reconstruction result from the adsorbate-substrate bond formation with sp-orbital hybridization and that the driving force behind the reconstruction originates from the electrostatic interaction along the <11> direction.
keywords: Chemisorption, chemical bond,reconstruction, STM, LEED
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碳,氮,氧诱导的镍铑(100)表面重构:表面键形成及应用
摘要:A brief review is given focusing on the nature, kinetics, dynamics and consequences of the sp-orbital hybrid bonding of C, N and O to the Ni/Rh(001) surfaces which give rise to the same kind of "radial and then the p4g clock" reconstruction . It is identified that the "radial" and the subsequent "clock" reconstruction result from the adsorbate-substrate bond formation with sp-orbital hybridization and that the driving force behind the reconstruction originates from the electrostatic interaction along the <11> direction.
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No.2391213761120698****
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碳,氮,氧诱导的镍铑(100)表面重构:表面键形成及应用
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