A Binuclear Isocyanide Iron Azadithiolate Relevant to the Active Site of Fe-Only Hydrogenases: Synthesis, Structure and Electrochemical Properties
首发时间:2006-11-13
Abstract:Diiron complexes 3 and 5 as mimics for the active site of the Fe-only hydrogenases have been synthesized. The structures were fully characterized by X-ray crystallography. The 4-iodophenylisocyanide ligands in 5 are in basal positions and are nearly parallel to each other, showing the π-π stacking interactions. The electrochemical properties of complexes 3 and 5 were investigated by cyclic voltammetry.
keywords: Fe-only hydrogenase, Bioinorganic chemistry, Diiron carbonyl, Isocyanide
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A Binuclear Isocyanide Iron Azadithiolate Relevant to the Active Site of Fe-Only Hydrogenases: Synthesis, Structure and Electrochemical Properties
摘要:Diiron complexes 3 and 5 as mimics for the active site of the Fe-only hydrogenases have been synthesized. The structures were fully characterized by X-ray crystallography. The 4-iodophenylisocyanide ligands in 5 are in basal positions and are nearly parallel to each other, showing the π-π stacking interactions. The electrochemical properties of complexes 3 and 5 were investigated by cyclic voltammetry.
关键词: Fe-only hydrogenase, Bioinorganic chemistry, Diiron carbonyl, Isocyanide
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A Binuclear Isocyanide Iron Azadithiolate Relevant to the Active Site of Fe-Only Hydrogenases: Synthesis, Structure and Electrochemical Properties
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