等离子体技术联合纳米TiO2光催化剂降解含苯废气
首发时间:2007-01-05
摘要:处理挥发性有机废气(Volatile Organic Compounds,简称VOCs)的传统方法对于新的环境条件来说存在着技术经济上的缺陷。近些年来一些新的处理技术得到了广泛的研究和发展,如生物法、光催化法和等离子技术等。纳米TiO2光催化技术,由于其运行能耗低,氧化性强,正受到日益普遍的关注。本实验研究将纳米TiO2光催化剂应用于等离子体反应器中,利用光催化剂和等离子体协同作用处理含苯废气。实验中通过自制纳米TiO2溶胶,并将其均匀镀在陶瓷拉西环表面,作为反应光催化剂,目标处理气体为含苯废气。论文中分别对光催化剂对含苯废气降解率的影响,不同烧结温度下光催化剂的性能比较,湿度对光催化剂的影响及光催化剂的失活与再生等因素进行了实验及分析。实验结果证明:光催化剂明显加强了等离子体反应器对含苯废气的降解效果。含苯废气入口浓度600mg/m3时,电场强度达到9kV/cm,去除率即提高到80%以上;入口浓度1500mg/m3时,电场强度12kV/cm,有光催化剂的情况比无催化剂的去除率提高了19%。纳米TiO2经450℃热处理呈锐钛矿晶型,此时光催化剂性能最好,光催化剂与等离子体协同作用处理含苯废气,其去除率可高达99%。
关键词: 纳米TiO2 光催化剂 介质阻挡放电 等离子体反应器
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Decomposition of benzene by plasma reactor
Abstract:The traditional methods of VOCs degradation which were referred to the new environmental condition had many disadvantages. In these years, some new technologies, such as biologic process, photocatalysis process, and plasma technology, were paid more and more attention. Especially, photocatalysis technology of nanometer TiO2 got extensive studies because of low energy consume and strong oxidation capability. Synergistic effect of atmospheric non-thermal plasma generated by dielectric barrier discharge (DBD) and nano-TiO2 photocatalyst on benzene decomposition was tested. Nano-TiO2 sol was done as photocatalyst, which was coated on the surface of rasching rings. The paper indicated the effect of photocatalyst on removal efficiency of benzene, the compare of photocatalyst characteristic in different high temperatures by heat treatment, the effect of humidity on photocatalyst characteristic, and the effect of inactivation and reactivation of photocatalyst on removal efficiency. The results showed that the effect of degradation was visible by added photocatalyst in the plasma reactor. When concentration of benzene was 600 mg/m3 and electrostatic field strength was 9 kV/cm, the removal efficiency of benzene was increased up to 80%. When concentration of benzene was 1500 mg/m3 and electrostatic field strength was 12 kV/cm, the removal efficiency was increased 19% higher with photocatalyst than without photocatalyst. Nano-TiO2 crystal was anatase crystal in 450℃ heat treatment. While the photocatalysis characteristic of anatase crystal was best and degradation efficiency was up to 99%.
Keywords: nanometer TiO2 photocatalyst dielectic barrier discharge the plasma reactor
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No.1059495359116796****
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