Synthesis, photophysical and electrochemical properties of a D-π-A ensemble derived from porphyrazine and tetrathiafulvalene
首发时间:2009-06-10
Abstract:Cis/trans 1,2-dicyanoethylenes bearing tetrathiafulvalene units linked by ethylenedithio spacer were prepared. The cis isomer was converted to eight tetrathiafulvalene unit substituted magnesium porphyrazine upon a metal-templated cyclotetramerization with magnesium propoxide in propanol. The dicyanoethylenes and target compound were characterized by EA, NMR, and MALDI-TOF mass and photophysical and Electrochemical propeties were discussed.
keywords: tetrathiafulvalene porphyrazine dicyanoethylene synthesis electrochemistry
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Synthesis, photophysical and electrochemical properties of a D-π-A ensemble derived from porphyrazine and tetrathiafulvalene
摘要:Cis/trans 1,2-dicyanoethylenes bearing tetrathiafulvalene units linked by ethylenedithio spacer were prepared. The cis isomer was converted to eight tetrathiafulvalene unit substituted magnesium porphyrazine upon a metal-templated cyclotetramerization with magnesium propoxide in propanol. The dicyanoethylenes and target compound were characterized by EA, NMR, and MALDI-TOF mass and photophysical and Electrochemical propeties were discussed.
关键词: tetrathiafulvalene;porphyrazine;dicyanoethylene;synthesis;electrochemistry
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No.3300615091244600****
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Synthesis, photophysical and electrochemical properties of a D-π-A ensemble derived from porphyrazine and tetrathiafulvalene
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