A composite based on {VO3}nn- chain containing two different types of organic ligands
首发时间:2012-01-06
Abstract:The title compound, [Cu(1,10-phen)(en)H2O][Cu(en)2]0.5[V3O9] (1,10-phen = 1,10-phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of one 1D {VO3}nn chain formed by corner-sharing VO4 tetrahedra and two different types of cations [Cu(1,10-phen)(en)H2O]2+ and [Cu(en)2]2+. The adjacent 1D {VO3}nn chain are further bridged by [Cu(en)2]2+ complexes through Cuo o oO weak interactions to form a 2D network.
keywords: Polyoxometalates Polyoxovanadates Network Cluster
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基于{VO3}nn-链连接两种有机配体的钒氧簇化合物
摘要:The title compound, [Cu(1,10-phen)(en)H2O][Cu(en)2]0.5[V3O9] (1,10-phen = 1,10-phenanthroline, en = ethylenediamine) (1) has been prepared by solution diffusion method. Compound 1 consists of one 1D {VO3}nn chain formed by corner-sharing VO4 tetrahedra and two different types of cations [Cu(1,10-phen)(en)H2O]2+ and [Cu(en)2]2+. The adjacent 1D {VO3}nn chain are further bridged by [Cu(en)2]2+ complexes through Cuo o oO weak interactions to form a 2D network.
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