煤的孔隙综合分形维数研究
首发时间:2013-12-24
摘要:选择北皂矿褐煤、蔡园矿气煤、西曲矿焦煤和古汉山矿无烟煤作为研究对象,采用压汞法和低温液氮吸附法分析煤的孔隙结构以及孔隙形态,计算了煤中不同孔径段的分形维数。压汞法计算结果显示,褐煤、气煤与焦煤孔径大于或等于10nm的孔径段具有明显的分形特征,孔径小于10nm的孔径段不具有分形特征;而无烟煤孔径大于或等于100nm的孔径段具有明显的分形特征,孔径小于100nm的孔径段不具有分形特征。液氮吸附法计算结果显示,孔径范围2.03~361.14nm的煤孔隙分形特征明显,其中以孔径10nm和100nm为界的分形维数有所不同。基与此,定义并计算了煤的孔隙综合分形维数,实现了煤孔隙全孔径分形维数的统一,便于对煤孔隙结构非均质性进行整体表征。
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Comprehensive fractal dimension of coal porosity
Abstract:Mercury intrusion porosimetry and nitrogen adsorption experiment were apllied to analyze the pore structure and morphology of the brown, gas, coking and anthracite coal samples respectively collected from the Beozhao, Caiyuan, Xiqu and Guhanshan mines. And the fractal dimensions of coal samples different pore sizes were calculated by the Mercury intrusion porosimetry and Nitrogen adsorption experimental data. The coal fractal dimension results in Mercury intrusion porosimetry show that the brown, gas, coking coal pore fractal characteristics is conspicuous when the aperture is greater than or equal to 10nm and it is less than 100nm about the anthracite coal, while it is not obvious when the aperture is less than 10nm and 100nm. And The coal fractal dimension results in Nitrogen adsorption show that the coal pore fractal characteristics is conspicuous when the aperture is greater than or equal to 2.03nm and less than or equal to361.14nm, but the fractal dimensions of coal samples are different with 10nm and 100nm threshold. On the basis of the above study, the coal porosity comprehensive fractal dimension was defined and calculated. Through this study, the fractal dimensions of the coal pore full aperture have been unified effectively and the coal pore fractal research has been improved. So it is convenient to the characterization of the non-uniformity of coal.
Keywords: coal pore mercury intrusion nitrogen adsorption fractal dimension
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