A Chiral Spin Crossover Metal-Organic Framework
首发时间:2014-01-08
Abstract:An unprecedented chiral metal-organic framework with spin crossover (SCO) property, [FeII(mptpy)2]?EtOH?0.2 DMF (1?nsolv), has been solvothermally synthesized through spontaneous resolution. It displays remarkable stability and two-step SCO under (Tc1 = 200 K) and above (Tc2 = 357 K) room temperature.
keywords: metal-organic framework chiral structure spin-crossover spontaneous resolution
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