An electrochemical sensing platform structured with ionic liquid assisting carbon nanohorns for 4-aminophenylarsonic acid determination
首发时间:2014-12-11
Abstract:In this paper, a evidently simple and sensitive electrochemical sensing platfolm structured with ionic liquid assisting carbon nanohorns to detecte 4-aminophenylarsonic acid. The excellent 4-aminophenylarsonic acid of organic arsenic sensor coating with ionic liquid assisted carbon nanohorns has been developed firstly. Due to prominent properties of large conjugate dahlia-like carbon nanohorns, such as good electric conduction, large surface area, high pore volume etc, and its synergistic action with ionic liquid, which is good dispersant with excellent ion conductivity , the sensor performed excellent sensing capabilities and specifically the corresponding sensing interface layer showed obvious electrocatalysis towards 4-aminophenylarsonic acid. The as-proposed sensor presented high sensitivity, wide dynamic response range, eximious stability and reproducibility. This paper inditacted that excellent sensing application of carbon nanohorns and ionic liquid formed for 4-aminophenylarsonic acid sensor holds potential utilized in practical applications.
keywords: electrochemistry ionic liquid carbon nanohorn 4-aminophenylarsonic acid
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一种由离子液体辅助碳纳米角构建的电化学传感平台对4-氨基苯胂酸的检测研究
摘要:在本文,一种由离子液体辅助碳纳米角体系构建的简宜和高灵敏度的电化学传感平台用于检测4-氨基苯胂酸。这种用离子液体辅助碳纳米角修饰的有机砷电化学传感器在电化学检测中首次应用。由于碳纳米角呈花形结构,表面具有非常多的配位点,化学特性为具有良好的电子导电性、大的比表面积和高的空隙容量。同时离子液体也是一种具有强的离子传导的分散剂,可以增强碳纳米角的电化学响应。所以利用离子液体辅助碳纳米角体系构建的电化学传感器界面对4-氨基苯甲酸具有电催化作用。文中的电化学传感器表现出高灵敏度、低检出限、动态范围宽、稳定性和重现性好的优点,有望更广泛地应用于实际检测中。
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No.4621759102261814****
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一种由离子液体辅助碳纳米角构建的电化学传感平台对4-氨基苯胂酸的检测研究
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