绒面皮革材料的超疏水化改性及性能研究
首发时间:2016-11-22
摘要:皮革制品长期放置于潮湿的环境中,会因吸收空气中的水而引起变形或遭到细菌侵蚀。因此,对皮革制品进行超疏水化改性具有重要的意义。采用聚二甲基硅氧烷(PDMS)对绒面革改性,进行超疏水表面的构筑。采用扫描电子显微镜对处理前后绒面革的微观形貌和粗糙度进行表征;通过视频光学接触角测量仪测试绒面革表面的润湿性能;对改性前后绒面革的透水汽性、断裂强力、断裂伸长率进行测试。研究PDMS的浓度、浸渍时间对绒面革超疏水性的影响,并通过考察物理摩擦作用对超疏水绒面革稳定性的影响。测试结果表明,改性后的绒面革表面的疏水性得到了显著提高,且经8000次的机械摩擦后仍具有超疏水性。
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Preparation and Properties of Superhydrophobic Suede Leather
Abstract:Leather can easily deform or suffer bacterial attack for a long time placement in a humid environment due to the absorbency of water from the air. Therefore, fabricating superhydrophobic leather coating is of great significance in practical application. In this study, polydimethylsiloxane (PDMS) was exploited to modify the suede leather, constructing superhydrophobic surfaces. The morphology and roughness of the suede leather was characterized by scanning electron microscopy. The wetting property of the suede leather was investigated by optical contact angle. At the same time, the water vapor permeability, breaking strength were also measured. The effect of PDMS concentration, immersion time on the superhydrophobicity of suede leather was also studied. Meanwhile, the stability of the superhydorphobic suede leather was evaluated by mechanical abrasion. The results showed that the hydrophobicity of the suede leather has been significantly improved after modification. Moreover, the superhydrophobicity of modified suede leather was capable of withstanding even 8000 cycles of abrasion.
Keywords: Suede leather superhydrophobic coating PDMS
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