聚酰亚胺/聚丙烯腈纤维在碳化过程中结构演变
首发时间:2017-05-16
摘要:采用湿法纺丝技术制备聚酰亚胺/聚丙烯腈(PI/PAN)纤维,经500-1500 ℃碳化得到PI/PAN基碳纤维,采用元素分析、X射线衍射、拉曼光谱、热重-红外联用等方法研究了碳化温度对PI/PAN基碳纤维结构和性能的影响。结果表明,随碳化温度升高,纤维结构向乱层石墨结构转变,且逐渐有序,最终得到碳含量96%,结构致密且导电优良的碳纤维。碳化过程中,PI/PAN纤维在500-700 ℃分子链开始断裂、分解,释放的气体主要是CO和CO2;随后分子链重组形成乱层石墨结构,900 ℃后的脱氮反应并加快了类石墨晶体的生长;1100 ℃后芳香片层增长速率变缓。并且提出PI/PAN基碳纤维结构演变机理。
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Structural evolution of the polyimide/polyacrylonitrile fibers during carbonization
Abstract:In this paper, polyimide/polyacrylonitrile (PI/PAN) fibers were prepared by wet-spinning method, following by carbonization at temperature ranging from 500 to 1500 ℃ to obtain PI/PAN-based carbon fibers. The effects of carbonization temperature on the structures and properties of PI/PNA-based carbon fibers were investigated by EA, XRD, Raman and TG-IR analyses. The results indicated that the graphite structure was formed and gradually became ordered by increasing carbonization temperature, finally resulting in carbon fibers with carbon content of 96%, compact structure and excellent electrical properties. During carbonization, the decomposition of the polymer chain of PI/PAN fibers occured in the temperature range of 500-700 ℃, and the CO and CO2 are predominant gaseous by-products at the initial stage. Whereafter, the turbostraticgraphitic structure were formed by the recombination of molecular chain. The growth of graphite-like crystal were accelerated by denitrification reaction at temperatures higher than 900 ℃. The aromatic layer increased gradually after 1100 ℃. Moreover, the mechanism of structural evolution of PI/PAN-based carbon fibers were proposed.
Keywords: fiber polyimide polyacrylonitrile carbonization
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No.4733875119294314****
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