The effects of carbon nanotubes on the mechanical and wear properties of AZ31 alloy
首发时间:2017-08-31
Abstract:Carbon nanotubes (CNTs) reinforced AZ31 matrix nanocomposites were successfully fabricated using powder metallurgy method followed by hot extrusion. And the influence of CNTs on microstructure, mechanical properties and wear properties were investigated systematically by the optical microscope (OM), scanning electron microscope (SEM), X-ray diffraction (XRD), hardness test, tensile test and wear test. The results revealed that the nanocomposites showed slightly smaller grain size compared to the matrix and uniform distribution of CNTs could achieved at proper content. The addition of CNTs could weaken basal plane texture. Besides, the yield strength and ultimate tensile strength of the composites were enhanced with increase the amount of CNTs up to 2.0wt.%, and reached the maximum values of 241MPa (+28.2%) and 297MPa (6.1%), respectively. But the failure strain was comprised gradually after adding CNTs. Load transfer mechanism, Orowan mechanism and thermal mismatch mechanism played important roles on the enhancement of the yield strength, and several classical models were employed to predict the theoretical values. The reasons attributed to the discrepancy between the theoretical values and experimental values were discussed in details. Besides, the effect of CNTs content on the friction coefficient and weight loss of the nanocomposites were also studied, and the prediction equations were also established by nonlinear fitting. The relationships between the CNTs content and the friction coefficient and weight loss could be described by the exponential decay model and Boltzmann model, respectively.
keywords: Carbon nanotube metal matrix nanocomposites texture strengthening mechanisms wear behavior
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碳纳米管对AZ31镁合金力学性能和磨损性能的影响研究
摘要:采用粉末冶金法结合热挤压成功制备了碳纳米管(CNTs)增强AZ31镁基纳米复合材料。通过光学显微镜(OM)、扫描电子显微镜(SEM)、X射线衍射(XRD)、硬度试验、拉伸试验和磨损试验系统研究了CNTs对复合材料微观组织、力学性能和磨损性能的影响。结果表明,与基体相比,纳米复合材料晶粒尺寸略有细化,且适量的碳纳米管可以实现在基体中均匀分布。碳纳米管的添加可以弱化基面织构。此外,复合材料的屈服强度和极限抗拉强度随着CNTs含量的增加而增加,在添加量为2.0wt.%时达到最大值,分别为241MPa(+ 28.2%)和297MPa(+6.1%)。但是,在添加碳纳米管之后延伸率逐渐降低。载荷传递机制、奥罗万机制和热错配强化对提高材料的屈服强度具有重要作用。本文采用了几种经典模型预测复合材料强度的理论值,并详细讨论了理论值和实验值差异的原因。此外,还研究了CNTs含量对纳米复合材料摩擦系数和失重的影响,并通过非线性拟合建立了预测方程。结果表明,CNTs含量与摩擦系数和重量损失之间的关系可以分别用指数衰减模型和玻尔兹曼模型来描述。
关键词: 碳纳米管 金属基体纳米复合材料 组织 加强机制 磨损行为
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