磷化钯/氮磷掺杂碳复合材料的制备及其氧还原性能研究
首发时间:2020-03-05
摘要:寻找能够高效改善燃料电池阴极上氧还原(ORR)缓慢动力学过程的非Pt催化剂迫在眉睫。本研究通过搅拌和煅烧方法合成出了Pd3P@NPC复合材料,并使用SEM、TEM、XRD、XPS等表征仪器分析其物理化学性质。将Pd3P@NPC催化剂运用于ORR性能测试,结果表明Pd3P@NPC的催化活性可与商业Pt/C相媲美,其半波电位为0.842 V,仅比Pt/C低9 mV,而质量活性却是Pt/C的3.05倍。Pd3P@NPC中的磷化钯颗粒和N,P掺杂的碳基底协同催化ORR,两者良好的导电性及其电子相互作用使得ORR催化活性大幅度提高。此外,由于碳基对磷化钯颗粒的支撑,磷化钯颗粒在催化过程中不易脱落,因此Pd3P@NPC具有极好的稳定性。本研究结果对开拓钯基ORR催化剂具有重要启示价值。
关键词: 电催化 氧化还原反应 磷化钯颗粒 杂原子掺杂碳 电子相互作用 协同催化
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Synthesis and Properties of Palladium Phosphide/N,P-doped carbon composites for Oxygen Reduction
Abstract:It is urgent to find a non-pt catalyst that can efficiently improve the sluggish oxygen reduction (ORR) kinetics on the fuel cell cathode.?In this study, Pd3P@NPC composite has been synthesized by themixingand calcination methods, and and its physical and chemical properties have been proved by means of SEM, TEM, XRD, XPS and other characterization instruments.Pd3P@NPC catalyst has been applied to the ORR performance tests, whichindicatePd3P@NPC possessescomparable catalytic activity with commercial Pt/C. The half-wave potential(0.842 V)of Pd3P@NPCis only 9 mV lower than Pt/C, and the mass activity of of Pd3P@NPCis3.05 times than that of Pt/C.?Palladium phosphide particles and N, P doped carbon in Pd3P@NPCcatalyze ORR synergistically, and their excellent electrical conductivity and electron interaction greatly enhance ORR catalytic activity.In addition, Pd3P @ NPC has remarkable stability due to the support of carbon substrate for the palladium phosphide particles, which makes it difficult to fall off during the catalytic process.?The results of this study have important enlightening value for exploiting Pd-based ORR catalysts.
Keywords: Electrocatalysis oxygen reduction reaction palladium phosphide nanoparticles heteroatoms doped carbon electronic interaction synergic catalysis
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磷化钯/氮磷掺杂碳复合材料的制备及其氧还原性能研究
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