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黄吉平

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期刊论文

Coalescence of Pickering Emulsion Droplets Induced by an Electric Field

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Phys. Rev. Lett.,2013,110(6):064502 | 2013年02月05日 | https://doi.org/10.1103/PhysRevLett.110.064502

URL:https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.110.064502

摘要/描述

Combining high-speed photography with electric current measurement, we investigate the electrocoalescence of Pickering emulsion droplets. Under a high enough electric field, the originally stable droplets coalesce via two distinct approaches: normal coalescence and abnormal coalescence. In the normal coalescence, a liquid bridge grows continuously and merges two droplets together, similar to the classical picture. In the abnormal coalescence, however, the bridge fails to grow indefinitely; instead, it breaks up spontaneously due to the geometric constraint from particle shells. Such connecting-then-breaking cycles repeat multiple times, until a stable connection is established. In depth analysis indicates that the defect size in particle shells determines the exact merging behaviors: when the defect size is larger than a critical size around the particle diameter, normal coalescence will show up, while abnormal coalescence will appear for coatings with smaller defects.

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