In this series of two papers we examine the classical problem of ranking a set of players on the basis of a set of pairwise comparisons arising from a sports tournament, with the objective of minimizing the total number of upsets, where an upset occurs if a higher ranked player was actually defeated by a lower ranked player. This problem can be rephrased as the so-called minimum feedback arc set problem on tournaments, which arises in a rich variety of applications and has been a subject of extensive research. In this series we study this NP-hard problem using structure-driven and linear programming approaches. Let be a tournament with a nonnegative integral weight on each arc e. A subset F of arcs is called a feedback arc set if contains no cycles (directed). A collection of cycles (with repetition allowed) is called a cycle packing if each arc e is used at most times by members of . We call T cycle Mengerian (CM) if, for every nonnegative integral function w defined on A, the minimum total weight of a feedback arc set is equal to the maximum size of a cycle packing. The purpose of these two papers is to show that a tournament is CM iff it contains none of four Möbius ladders as a subgraph; such a tournament is referred to as Möbius-free. In this first paper we present a structural description of all Möbius-free tournaments, which relies heavily on a chain theorem concerning internally 2-strong tournaments.