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期刊论文

Suppression of undesired peaks due to residual intermolecular dipolar interactions in liquid NMR

蔡淑惠Zhong Chen ab* Xiaoqin Zhu a Shuhui Cai a Jianhui Zhong b

Chemical Physics Letters 417(2006)48-52,-0001,():

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摘要/描述

Residual intermolecular dipolar interactions may result in undesired spectral features on highly concentrated samples in liquid NMR. Although homonuclear decoupling can be employed to suppress the interactions, it may cause a strong irradiation peak, which obscures the nearby peaks. In order to overcome this shortcoming, a modified CRAZED sequence with three radio-frequency pulses was proposed. The analytical expression derived from the dipolar field treatment was employed to select proper flip angles and phase cycling. Theoretical predictions, experimental observations, and computer simulations demonstrated that the new method effectively suppresses the undesired peaks due to residual dipolar effects.

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