In this paper, the Influences of electrical field on boiling-condensation heft transfer system have been investigated using a cylinder beat transfer model Freon-ll is selected as working fluid. The condensation heat transfer coefficient, the boiling heat flux the saturation pressure are meassured in this investigation. According to the experimental results, it is found that the electrical field can influence best transfer system. The boiling heat transfer is enhanced by the applied voltage, and the saturate vapor of working fluid is condensed on the high voltage electrode directly when the applied voltage is higher than 6kv. The experimental results have been discussed, and it is considered that the high electrical field strength change the thermal properties of working fluid.