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期刊论文

DI- AND TRITERPENOIDS FROM TRIPTER YGIUM HYPOGLA UCUM

段宏泉HONGQUAN DUAN KAZUYOSHI KAWAZOE MASAHIKO BANDO* MASARU K]DO* and YOSHIHISA TAKAISHI†

Ph.vtochemistry, Vol. 46, No.3, pp. 535~543, 1997,-0001,():

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摘要/描述

The methanol extract of dried root outer bark of Tripterygium hypoglaucum (Levl.) Hutch afforded five new triterpenes: 2,3-seco-2,24-epoxy-D:A-friedoolenane-2, 24-olide-29-oic acid named celastolide, 2,23-dihydroxy-3-methoxy-6-oxo-l,3,5(10), 8-tetraene-24-nor-D:A-friedoolenane-29-oic acid, 2-hydroxy-3-methoxy-6-oxo-l,3,5(10), 8-tetraene-24-nor-D:A-friedoolenane-29-oic acid, 2,3-dihydroxy-l,3,5(10), 8-tetraene-24-nor-D: A-friedoolenane-29-oic acid and 3fl, 11 e-dihydroxy- 13(18)-ene-oleanane named triptohypol A, B and C and hypodiol, and two new diterpenes: 3/3,14,19-trihydroxy-abieta-8,11,13-triene and 7-oxo-I 1,13-dihydroxy- 19(4-3)-abeo-abieta-3,8,11,13-tetraene-19,18-olide named triptobenzene J and K. and 18 known compounds. Their structures were established on the basis of chemical and spectroscopic studies.

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