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期刊论文
Effects of Aromatic Substitutions on the Photoreactions in Mg+(C6HnF2X4-n) (X=F, CH3) Complexes: Formation and Decomposition of Benzyne Radical Cations Introduction
J. Phys. Chem. A 2004, 108, 3356-3366，-0001，（）：
Photoinduced reactions have been systematically studied on mass-selected complexes of Mg+ with tri-and tetrasubstituted benzene by F and/or CH3. The complexes fall into two groups. The Group I complexes involve bidentate coordination of the o-F atoms to Mg+, whereas the Group II complexes feature the linkage of Mg+ to only one of the F atoms. The o-benzyne radical cations were found to be the predominant photolysis products from the Group I complexes, but the yields of the benzyne radical cation products were low for Group II. For each group of complexes, different substituents, including CH3 (medium
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