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期刊论文
Seco-Prezizaane-Type Sesquiterpenes and an Abietane-Type Diterpene from Illicium minwanense
J. Nat. Prod. 2003, 66, 799-803,-0001,():
A methanol extract of the pericarps of Illicium minwanense afforded seven new seco-prezizaane-type sesquiterpenes (2-8) and a new abietane-type diterpene (9), together with six previously known compounds (1 and 10-14). The structures of the new compounds, (1S*)-and (1R*)-minwanenone (2 and 3), 1Rhydroxy-6-deoxypseudoanisatin (4), (2S)-hydroxy-6-deoxypseudoanisatin (5), 3-oxopseudoanisatin (6), (3S*, 6R*)-4, 7-epoxy-6-deoxypseudoanisatin (7), 7-O-methylpseudomajucin (8), and (+)-8, 11, 13, 15-abietatetraene (9), were elucidated by spectroscopic data analysis and chemical transformations. The absolute configurations of 1 and 5 were established by X-ray crystallographic analysis of their p-bromobenzoyl derivatives.
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