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李海洋

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期刊论文

LUMO-derived band structure of K3C60

李海洋Li HN Xu YB Bao SN Li HY He PM Zhang JH Wang J Qian HJ Liu FQ

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摘要/描述

K3C60 single-crystal film was prepared on the cleaved (111) surface of C-60 single crystal. Synchrotron radiation angle-resolved photoemission spectra were measured at normal emission with sample temperature at similar to 150 K. Up to four subpeaks of LUMO-derived bands were observed. These subpeaks exhibit distinct energy dispersions which resemble, in general, the theoretical ones calculated for K3C60 at low temperature with the so-called one-dimensional disordered structure. But there is a large deviation of experimental subband intervals from the theoretical values. By considering the influence of the Coulomb energy of K+ ion and the valence electron, the deviation, at least for the order of magnitude, is interpreted. This result is meaningful for the studies of the physical properties of alkali-doped C-60 solids, e.g., the mechanism for superconductivity. Better interpretations for the experimental band dispersions demand further research work, some possible directions of which are suggested.

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【免责声明】以下全部内容由[李海洋]上传于[2006年05月18日 18时44分39秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

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