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期刊论文

Formation and STM tip-induced reduction of ultra thin SnO film on Au (111)

毛秉伟J.W. Yan a Z.X. Xie b Z.X. Cao b C.J. Zhou c J.Y. Kang c B.W. Mao b*

Chemical Physics Letters 373(2003)575-579,-0001,():

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摘要/描述

This Letter presents a study on the oxidation of electrochemically deposited Sn monolayer on Au(1 1 1) surface and STM tip-induced reduction of as-prepared ultra thin SnO film. A threshold bias of 0.6 V (tip negative) at a low tunneling current of ~50 pA is required to image the as-formed SnO thin film by STM, typical of a semiconductor characteristic. Increasing the tunneling current to ~2 nA leads to the reduction of the SnO back to Sn. Based on the energy level calculation for the SnO, a mechanism involving direct electron tunneling is proposed to account for the tipinduced reduction.

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