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期刊论文
Process integration of H2O2 generation and the ammoximation of cyclohexanone
F Chem Technol Biotechnol 79: 658-662，-0001，（）：
The possibility of the integration of the processes ofH2O2 generation through isopropanol partial oxidation and ammoximation of cyclohexanone with H2O2 and NH3 TS-1 catalysed was investigated. The ammoximation of cyclohexanone over TS-1 with isopropanol as solvent was first studied. The results show that isopropanol can be used as solvent, and the impurities in the H2O2 solution obtained through isopropanol oxidation with only acetone needing to be separated have no harmful effects on the ammoximation of cyclohexanone, suggesting that the process of H2O2 generation through isopropanol oxidation and the ammoximation of cyclohexanone could be directly integrated.
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