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期刊论文

Synthesis and thermal degradation of biodegradable polyesteramide based on e-caprolactone and 11-aminoundecanoic acid

钱志勇Zhiyong Qian Sai Li Yi He Cao Li Xiaobo Liu*

Polymer Degradation and Stability 81 (2003) 279-286,-0001,():

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摘要/描述

A new kind of polyesteramide copolymer based on e-caprolactone and 11-aminoundecanoic acid has been synthesized by melt polycondensation. The copolymers were characterized by FTIR, 1H-NMR, DSC, and WAXD. With the increase in aminoundecanoic acid content, the melting temperature, heat of fusion, and Td,50% increased accordingly. The thermal degradation of the P(CL/AU)x/y copolymers was studied using FTIR, and TG During thermal degradation, the ester bond decomposes at lower temperature, then the amide bond decomposes at higher temperature.

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