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期刊论文

Studies on the mechanisms of the reactions between ethanol and D2O by arc-discharge

邵春林Huai-bin Shi* Chun-lin Shao Zeng-liang Yu

H.-b. Shi et al./Nucl. Instr. and Meth. in Phys. Res. B 194(2002)141-150,-0001,():

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摘要/描述

An arc-discharge was carried out to a mixture of ethanol and heavy water under a nitrogen atmosphere. GC-MS analysis showed that DCH2CH2OH and DOCH2CH2OH were produced. This result implies the decomposition of water molecules, which possibly serves as an initial step for the reaction in aqueous solution. In addition, CH3COOD and HOCH2CH2ND2 were also identified in the products, and it was considered that the "nitrogen deposition" effect was caused by capture of D from D2O with N

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