您当前所在位置: 首页 > 学者

沈伯雄

  • 59浏览

  • 0点赞

  • 0收藏

  • 0分享

  • 630下载

  • 0评论

  • 引用

期刊论文

Pyrolysis of scrap tyres with zeolite USY

沈伯雄Boxiong Shen∗ Chunfei Wu Rui Wang Binbin Guo Cai Liang

Journal of Hazardous Materials B137(2006)1065-1073,-0001,():

URL:

摘要/描述

A zeolite catalyst of ultrastable Y-type (USY) was investigated in the research of two staged pyrolysis-catalysis of scrap tyres. Scrap tyres were pyrolysed in a fixed bed reactor and the evolved pyrolysis gases were passed through a secondary catalytic reactor. The main objective of this paper was to investigate the effect of zeolite USY on the yield of products and the composition of derived oil. The influences of several parameters such as pyrolysis temperature, catalytic temperature, catalyst/tyre ratio, heating rate, etc. on the yield of the derived oil, char and gas were investigated. It showed that the increase of catalytic temperature and catalyst/tyre ratio resulted in high yield of gas at the expense of the oil yield. For example, when the catalyst/tyre ratio increased from 0.25 to 1.0, the yield of gas increased from 30.5 to 49.9 wt.%, and the oil yield decreased nearly two-fold from 31.6 to 12.7 wt.%. The concentration of light naphtha (boiling point < 160℃) was also investigated in this study. And the high catalyst/tyre ratio favored to increase the concentration of light naphtha (<160℃) in oil. In order to study the composition of derived oil, a distilled fraction (<280℃), which was 92.5 wt.% of the oil obtained from catalytic pyrolysis of scrap tyre at a pyrolysis temperature, catalytic temperature and catalyst/tyre ratio of 500, 400℃ and 0.5, respectively, was analyzed with gas chromatography/mass spectrometry (GC/MS). The distillate was found to contain 1.23 wt.% benzene, 9.35 wt.% toluene, 3.68 wt.% ethylbenzene, 12.64 wt.% xylenes, 1.81 wt.% limonene and 13.89 wt.% PAHs, etc., where the single ring aromatics represented a significant potential use as chemicals.

关键词: Pyrolysis Tyres Catalysis USY

【免责声明】以下全部内容由[沈伯雄]上传于[2011年04月07日 09时08分14秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

我要评论

全部评论 0

本学者其他成果

    同领域成果