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期刊论文

An adsorption strength model for the electrochemical codeposition of a-Al2O3 particles and a Fe±P alloy

王殿龙D. L. WANG J. LI* CH. S. DAI and X. G. HU

JOURNAL OF APPLIED ELECTROCHEMISTRY 29(1999)437-444,-0001,():

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摘要/描述

An adsorption strength model is developed to describe the mechanism of codeposition of a-alumina and Fe±P alloy. Based on hypotheses concerning the effective adsorption and the distribution of the adsorption strength of particles on the cathode, a general expression relating the content of em-bedded particles to the suspension concentration and the current density is deduced. This relationship is in good agreement with the experimental results. The variation of the content of particles in deposits with current density is an overall balance of two opposing а-ects which leads to a maximum in the particle content against current density curve.

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