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引用
期刊论文
Zinc-Mediated Radical Reactions of Per-(or Poly)fluorophenyl Aromatic Aldimines in Aqueous Media
SYNTHESIS 2004, No.5, pp 0683-0691,-0001,():
The intermolecular additions of alkyl halides to per-(or poly)fluorophenyl aromatic aldimines using zinc as a single-electron-transfer radical initiator have been studied in aqueous media. The reaction proceeds well for imines with different substituents at room temperature under air atmosphere and the corresponding fluorine-containing amines and 1,2-diamines are obtained in poor to good yields. A tentative reaction mechanism is proposed.
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