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王绍武
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期刊论文
Substituents effect on molecular structures of 13-vertex closo-metallacarboranes of rare earths. Synthesis and structural characterization of metallacarboranes bearing nidoand arachno-carborane ligands
Tetrahedron 59 (2003) 10373-10380，-0001，（）：
Several new 13-vertex closo-metallacarboranes of rare earths incorporating nido-and arachno-carborane ligands have been prepared and structurally characterized. They represent a new class of metallacarboranes bearing a h7-carboranyl ligand recently discovered in our laboratory. This work indicates that the substituents on carborane cage carbons may affect the overall molecular structures of the resultant 13-vertex closo-metallacarborane complexes, but have little influence on the interactions between the central metal ion and nido- or arachno-carborane ligand.
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