Aqueous solutions containing a high yield of suspended gold nanorods with mean aspect ratio 2.5 have been synthesizeed via an electrochemical method. The fluoresconco emission peaks fixed at 37Onm and 67Onm are due to the local field enhancement via coupling to the transverse and longitudinal urface plasmon resonarce. The qUasi-static calculation results indicate that with the increasing aspect ratio of the nanorods, the longer wavelength emission peak decreases and red shifts, wheresas the shorter wavelenth emission peak blue shifts slightly.