X-ray luminous radio-quiet high redshift QSOs are rare and can be used for the investigation of several important astronomical questions. We have conducted a large area survey for radio-quiet high redshift QSOs in the ROSAT All-Sky Survey, from which QSO candidates are selected using the digitized objective prism spectra from the Hamburg Quasar Survey. The 22 candidates with Galactic latitudes larger than 35o were observed with the 2.16m telescope at Xinglong station of Beijing Astronomical Observatory. Among the 19 new QSOs in our sample, six are radio-quiet QSOs with redshifts larger than 1.3 and three of them have redshifts larger than 2. Thus we have doubled the number of known X-ray luminous, radio-quiet high redshift QSOs in the surveyed sky area. The distribution of f1:4GHz=f1keV of radio-loud and radio-quiet QSOs in this area shows two well separated peaks. This can be taken as an evidence for different emission mechanisms of the observed X-rays in the two subgroups.