您当前所在位置: 首页 > 学者

邢献然

  • 34浏览

  • 0点赞

  • 0收藏

  • 0分享

  • 332下载

  • 0评论

  • 引用

期刊论文

Novel thermal expansion of lead titanate

邢献然XING Xianran DENG Jinxia CHEN Jun and LIU Guirong

RARE METALS Vol. 22, No.4, Dec 2003, p. 1,-0001,():

URL:

摘要/描述

Lattice parameters of lead titanate were precisely re-determined in the temperature range of −150-950℃ by high precision XRPD measurements. It was clarified that there was no any evidence for a new phase transition at low temperatures. Tetragonal distortion strain decreases with temperature increasing. A novel thermal expansion was observed, positive thermal expansion from −150℃ to room temperature (RT) and above 490℃, and the negative thermal expansion in the temperature range of RT-490℃. A big jump of thermal expansion coefficient is attributed to the tetragonal-cubic phase transition. A rationalization for the negative thermal expansion of PbTiO3 is due to the decrease of anion-anion repulsion as polyhedra become more regular at heating. The mechanisms of positive and negative thermal expansions were elucidated as the same nature in the homogenous tetragonal phase at present case.

【免责声明】以下全部内容由[邢献然]上传于[2005年03月08日 00时48分35秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

我要评论

全部评论 0

本学者其他成果

    同领域成果