We propose an approach to optimally synthesize quantum circuits from non-permutative quantum gates such as Controlled-Square-Root–of-Not (i.e. Controlled-V). Our approach reduces the synthesis problem to multiple-valued optimization and uses group theory. We devise a novel technique that transforms the quantum logic synthesis problem from a multi-valued constrained optimization problem to a group permutation problem. The transformation enables us to utilize group theory to exploit the properties of the synthesis problem. Assuming a cost of one for each two-qubit gate, we found all reversible circuits with quantum costs of 4, 5, 6, etc, and give another algorithm to realize these reversible circuits with quantum gates.