A brass block was constructed as a test block to study the Marangoni condensation in this paper. The maximal temperature difference of the block surface on which pure steam condensed was 11℃ when the block was cooled by the normal temperature water. Regulations and modes of Marangoni condensation for mixture vapor with different mass fractions were studied when the speed of vapor was 0.3m/s. As both temperature gradients and concentration gradients exist on the condensing surface, the experimental results indicate that the maximal heat transfer coefficient of mixture vapor can be 2.8 times that of pure steam when the Marangoni condensation of mixture vapor appears. The heat transfer coefficient of mixture vapor increases with the decrease of surface subcooling, and it appears a steep increase when the surface subcooling is small enough; the heat transfer flux has a maximum value as the surface subcooling rises; and the different modes of condensation are confirmed when the different ethanol concentration and different surface subcooling exist.