In a streamer dominated pulse corona the energetic electrons can interact with the gas molecules and produce radicals. Emission of second positive band (SPB) of the nitrogen, which was considered to orrespond to local yield of N radical, was monitored in this study for analyzing Nradical effect on removal of itrogen oxidex (NOx) from exhaust gases. It was found that the length of high luminous region (HLR) is related to energy efficiency of NOx removal. It was also testified that total emission intensity of SPB is linearly proportional with NOx removal in No/N2 mixture gas. Analysis of experimental data shows that the NOx removal energy efficiency is smaller when pulse width is longer. The energy efficiency also decreases with the increase of injected power and length of HLR, respectively. It was assumed that the local concentrated production of N radical in HLR is not effectively used for NO removal in the condition of low initial NOx concentration. It is concluded that the luminescence analysis provides a good method to understand NOx removal process in pulse discharge co-rona.