傅相锴
有机化学、精细化工、有机合成、有机磷化学、络合催化和功能材料等领域
个性化签名
- 姓名:傅相锴
- 目前身份:
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学术头衔:
博士生导师
- 职称:-
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学科领域:
有机化学
- 研究兴趣:有机化学、精细化工、有机合成、有机磷化学、络合催化和功能材料等领域
傅相锴,男,1945年12月生,四川宜宾市人,汉族。1967年7月四川大学化学系本科毕业;1981年四川大学化学系有机化学专业研究生毕业,获理学硕士学位。1984年2月至1986年5月在美国洛杉矶南加州大学化学系作访问学者,指导教师G.A.Olah教授是1994年诺贝尔化学奖获得者。现任西南大学教授,四川大学兼职教授,西南大学应用化学研究所所长,博士生导师。西南大学理科学术委员会委员,西南大学科协委员,西南大学理科学报编委会委员,重庆市重点学科应用化学学科负责人、学术带头人,重庆市高校重点实验室应用化学实验室主任,重庆市重点课程有机化学课程学术带头人;重庆市第一届学术和技术带头人,重庆市学术和带头人评委会委员,重庆市学位委员会第一届学科评议组成员。重庆市粘结学会副理事长、重庆市涂装学会专家咨询委员会副主任委员、全国功能材料学会常务理事。社会兼职:重庆市第一届、第二届政协委员,常委;民革重庆市第一届、第二届委员会委员、常务委员、副主任委员。
傅相锴长期从事有机化学、精细化工、有机合成、有机磷化学、络合催化和功能材料等领域的教学、科研工作。开拓了功能化的有机磷酸盐新型催化剂的研究领域并创出了特色,在国内外产生较大影响;新型水溶性和负载型膦氮配体和过渡金属络合催化剂方面的研究、超分子插层材料及低功耗光-电高效转换节能材料等领域的研究在国内外处于先进水平;研制出我国第一款电子纸模型样机,连续参加2003-2005年多届重庆高交会展出,填补了我国在该领域的研究空白,在理论有机化学领域的部分研究成果已编入高校教材。主持3项国家自然科学基金项目和十数项省部级重点科研、攻关科研项目。在国内外学术刊物上发表学术论文约200篇,50多篇论文为SCI和EI收录。申请发明专利11项,已获得发明专利授权4项。2003年主编高等教育出版社教材《高等有机化学》一部。1991年获四川省教委表彰为“做出突出贡献的中国硕士学位获得者”,1992年获国务院政府特殊津贴。主讲的《有机化学》课程于2003年评为重庆市精品课程。
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引用
傅相锴, Yan Sui, , Xiangkai Fu, Xuebing Ma, Jingrong Chen, Renquan Zeng
Y. Sui et al. Reactive & Functional Polymers 64 (2005) 55-62,-0001,():
-1年11月30日
New types of phosphonous acid-terminated oligomers oligo-polystyrenylphosphonous acid (PSPA) were prepared by free radical reaction between styrene and hypophosphorous acid and characterized by IR, MS, GPC and terminal group analysis. The initiator had great influence upon the average molecular weights and structure of dominate product. The average molecular weights of PSPA I (AIBN as initiator) was obviously higher than that of PSPA II (BPO as initiator). MS data showed that there were three series of polystyrenyl compounds for PSPA I, five series for PSPA II.The main product was H-[CH(C6H5)CH2]n-PO2H2 for PSPA I and C6H5CO2-[CH2CH(C6H5)]n–PO2H2 or C6H5CO2-[CH(C6H5)CH2]n–PO2H2 for PSPA II. Different free radical reaction mechanisms with AIBN or BPO as initiator were proposed according to the results of MS, IR and fn analysis.
Polymer, Phosphonous acid-terminated oligostyrene, Initiator, Reaction mechanism
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傅相锴, Xinjun Wu, Xuebing Ma, Yeling Ji, Qiang Wang, Xiao Jia, Xiangkai Fu
X. Wu et al. Journal of Molecular Catalysis A: Chemical 265 (2007) 316-322,-0001,():
-1年11月30日
A readily available (1S,2R)-(+)-2-amino-1,2-diphenylethanol and (1R,2S)-(−)-2-amino-1,2-diphenylethanol were immobilized on the layered zirconium phosphonates and the hybrid chiral zirconium phosphonates framework had been synthesized for the first time. The solid catalysts were characterized by IR, AFM, TG, XRD and elemental analysis. AFM showed that the self-assembled structure of chiral organic ligands on the surface of zirconium phosphonates 4 lined up regularly and homogeneously at 1.1 nm distance. XRD data indicated that zirconium phosphonate 4 was semi-crystalline with the interlayer space 20.11Å. Zirconium phosphonates 4 enantioselectively catalysized the addition of Et2Zn to benzaldehyde to afford optical secondary alcohol in>90% yield and 51%e.e. which only decrease at 6% enantiomeric excess lower than the corresponding chiral ligand (1R,2S)-(−)-2 in homogeneous asymmetric catalysis.
Self-assembled, Chiral, Immobilized, Zirconium phosphonate, Enantioselective addition
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引用
傅相锴, RenQuan Zeng, , XiangKai Fu, ChengBin Gong, Yan Sui, XueBing Ma, XinBin Yang
R. Zeng et al. Journal of Molecular Catalysis A: Chemical 229 (2005) 1-5,-0001,():
-1年11月30日
A new type of the mixed zirconium phosphate phosphonate support and the solid base were prepared and characterized by elemental analysis, IR, XRPD, 31P MAS NMR, TG, DTG and DSC. IR spectra showed that there were some differences between the support and the solid base in the vibration frequencies. XRPD indicated that the supports were amorphous. The 31P MAS NMR spectrum of each solid base exhibited three main resonances, and thermogravimetry indicated that the solid base had two or three step weight loss at temperatures of up 900℃. The Knoevenagel condensation of benzaldehyde with diethylmalonate or malononitrile, cyclohexanone with malononitrile was catalyzed by the solid base (H−=12.2) in high catalytic activity and simple work-up, the catalyst could be reused four times and easy to be regenerated.
The mixed zirconium phosphate phosphonate, Support, Solid base, Heterogeneous catalysis, Knoevenagel condensation
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