丁世良
分子动力学的研究工作,其内容包括原子分子间的量子散射,分子与表面的量子散射,分子与强激光场的相互作用,分子的高振转激发态能谱和解析势函数,以及分子的化学反应等
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- 姓名:丁世良
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学术头衔:
博士生导师
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学科领域:
原子分子物理学
- 研究兴趣:分子动力学的研究工作,其内容包括原子分子间的量子散射,分子与表面的量子散射,分子与强激光场的相互作用,分子的高振转激发态能谱和解析势函数,以及分子的化学反应等
丁世良,男,教授,经国家学位委员会批准为博士导师,分子科学学报编委,理论化学计算国家重点实验室学术委员会委员,山东省专业技术拔尖人才,吉林大学兼职教授。1962年毕业于山东大学物理系理论物理专业。1982.1--1984.6在美国Texas大学化学系R.E.Wyatt教授研究组做博士后工作,研究分子动力学及多光子过程,1990.2--1990.4在美国Texas大学化学系做短期访问,1993.12--1994.6应R.D.Levine邀请在以色列希伯来大学物理化学系分子动力学研究中心做访问教授,与R.D.Levine教授合作,用李代数李群方法研究分子的高振动激发和解析势能函数。多年来一直从事分子动力学的研究工作,其内容包括原子分子间的量子散射,分子与表面的量子散射,分子与强激光场的相互作用,分子的高振转激发态能谱和解析势函数,以及分子的化学反应等。参加国家自然科学委资助的“七五”和“八五”期间的两项重大项目的研究工作。负责完成或正在执行五项国家自然科学基金项目。曾获国家教委科技进步二等奖三次(1988,1990,1992),获教育部科技进步三等奖一次(1999)。所指导的博士论文获山东省优秀博士论文奖(2000),已培养8名博士,16名硕士,所发表论文100余篇。
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10
丁世良, Meishan Wang, Shiliang Ding, * Dongtai Feng, and Haiying Liu
PHYSICAL REVIEW A, 66, 022506(2002),-0001,():
-1年11月30日
Using Lie-algebraic techniques and the simpler expressions of the matrix elements of Majorana operators given by us, we obtain an effective Hamiltonian operator which conveniently describes vibrational spectra of linear tetratomic molecules, including both stretching and bending modes. For a linear symmetrical four-atom molecule C2H2, the highly excited vibrational levels are obtained by applying the u (4) algebraic approach. We have found that the spectra are made up of a clustering structure. The number of levels in one cluster depends on the total quantum number of stretching and bending vibrations. In addition, some other properties, such as the level assignment and the labeling of calculated theoretical results, are also discussed.
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【期刊论文】Vibrational spectra of HCN and OCS from second-order expansion of the U1(4)⊗U2(4) algebra
丁世良, Yujun Zheng, Shiliang Ding
Physics Letters A 256(1999)197-204,-0001,():
-1年11月30日
The vibrational excitations of linear triatomic molecules, including both bending and stretching vibrations, are studied in the framework of dynamical symmetry groups. In this framework, the dynamical symmetry group of triatomic molecules is U1(4)⊗U2(4). Hence, a Hamiltonian is constructed that includes the second-order combination of the invariant operators. The eigenvalues of the molecular Hamiltonian give relatively little improvement for HCN but significant improvement for OCS. We obtained highly excited vibrational levels of the two molecules.
Dynamical symmetry group, Lie algebra, Vibrational spectra, HCN, OCS
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丁世良, Ying Dai a, *, Shiliang Ding b
Journal of Molecular Structure (Theochem) 528(2000)85-90,-0001,():
-1年11月30日
In this paper, the multiphoton transition Hamiltonian for the linear triatomic molecule HCN is given by using the quadratic anharmonic model and Sudden approximation. From this Hamiltonian we find a dynamic algebra h4. The bond-selective vibrational transition probability of HC and the long-time averaged energy are calculated.
Lie algebra, Multiphoton transition, Selective vibrational excitation
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【期刊论文】Algebraic Description of Stretching and Bending Vibrational Spectra of H2O and H2S
丁世良, Yujun Zheng and Shiliang Ding
Journal of Molecular Spectroscopy 201, 109-115(2000),-0001,():
-1年11月30日
The vibrational excitations of bent triatomic molecules, including both bending and stretching vibrations, are studied in the framework of the U (4) algebra. For the bent triatomic molecules H2O and H2S, the highly excited vibrational levels (up to 14) are obtained using the U (4) algebraic approach. We have found that the spectra are made up of clustering structure. The number of levels in one cluster depends on the total quanta of stretching and bending. In addition, some other properties are also discussed.
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【期刊论文】Time-independent energy-sudden transformationa
丁世良, Shi-Liang Ding b) and Robert E. Wyatt
J. Chem. Phys. 78 (9), 1 May 1983,-0001,():
-1年11月30日
The time-independent energy sudden (ES) representation is defined through application of the energy shift operator S=exp[-(h-ωn)ə/əє], where h is the internal (molecular) Hamiltonian. Our introduction of S follows from an earlier study by Chang, Eno, and Rabitz where exp[-iht], which "factors out" internal motion, was used to define the time-dependent ES representation. Exact integral equations for the scattering wave function within the ES representation are derived, the leading terms being the approximate ES wave function. Corrections to the ES wave function are nonsingnlar and involve the generalized potential increment V=S-1VS-V, where V is the interaction potential. Boundary conditions and transition amplitudes are discussed, as is the connection between wave functions in the ES and the original representations.
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【期刊论文】Lie algebraic approach to potential energy surface for symmetric triatomic molecules
丁世良, Shiliang Ding a) and Yujun Zheng
JOURNAL OF CHEMICAL PHYSICS VOLUME 111, NUMBER 10, 8 SEPTEMBER 1999,-0001,():
-1年11月30日
Potential energy surfaces play an important role in studying theoretical chemistry. In this work, the expression of the potential energy surface containing information about the bending motion of triatomic molecules is derived by using the semiclassical limit of the algebraic Hamiltonian with the dynamical symmetry group U1(4)⊗U2(4). And, we also obtain the force constants. The method can be applied to a number of stable triatomic molecules, such as, H2O, H2S.
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【期刊论文】Lie algebraic approach to potential energy surface for symmetrical linear tetratomic molecule
丁世良, Xiaoyan Wang a, Shiliang Ding a, b, *
Chemical Physics 297(2004)111-119,-0001,():
-1年11月30日
Using Lie algebraic method, we obtain the fitting coefficients of an effective Hamiltonian operator, which conveniently describes vibration spectra of symmetrical linear tetratomic molecules, including both stretching and bending modes. With the classical limit of the Hamiltonian and the kinetic energy equal to zero, we get the potential energy surface of the linear symmetry tetratomic molecule. For an example, we use the method to calculate the potential energy surface of C2D2. We fit 41 data with 7 coefficients; the data are from Iachello et al. [J. Mol. Spectrosc. 149 (1991) 132]. The fitting rms is 6.68cm-1. At last, we use the potential energy surface to get the force constants and the dissociation energy. The method can be applied to a number of linear symmetry tetratomic molecules.
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丁世良, Zhi-Hui Geng a, Ying Dai a, b, *, Shi-Liang Ding c
Chemical Physics 278(2002)119-127,-0001,():
-1年11月30日
The multiphoton rovibrational excitation of diatomic molecule in intense laser fields is studied by using simulated potential and Lie algebraic approach. The rovibrational transition probability as a function of external field frequency and time, respectively, for the molecules HF, NO and LiH is calculated. The influences of the rotation on the multiphoton processes are investigated.
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【期刊论文】Algebraic approach to the potential energy surface for the electronic ground state of ozone
丁世良, Yujun Zheng *, Shiliang Ding
Chemical Physics 255(2000)217-221,-0001,():
-1年11月30日
A potential energy surface for the electronic ground state of the O3 molecule is obtained using U (4) group. This potential energy surface includes the information of bending motion. Additionally, some properties, for example, saddle points, are discussed.
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丁世良, Yujun Zheng, Shiliang Ding
Chemical Physics 247(1999)225-235,-0001,():
-1年11月30日
The potential energy surfaces of nonlinear triatomic molecules are determined by the U (4) algebraic method. The combination coefficients in the Hamiltonian are gotten from fitting the spectroscopic data. The molecular properties, such as, force constants and dissociation energies, are obtained in terms of the potentional energy surfaces. The results for the SO2 molecule are in good agreement with the experimental results and other theoretical results.
Potential energy surface, Lie algebraic method, Nonlinear triatomic molecules, Excited vibrational levels
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