李靖
1. 过渡金属双核及多核络合物的研究 2. 含金属基团的聚合物的设计、合成、结构及性能研究 3. 绿色化学
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- 姓名:李靖
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学术头衔:
博士生导师
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学科领域:
有机化学
- 研究兴趣:1. 过渡金属双核及多核络合物的研究 2. 含金属基团的聚合物的设计、合成、结构及性能研究 3. 绿色化学
李靖,教授,男,1963年出生,1982年毕业于南开大学化学系,1982-1988就读于南开大学元素有机化学研究所,1985年获硕士学位,1988年获博士学位。1988至今在南开大学元素有机化学研究所工作。1992-1994年在西班牙Oviedo大学从事博士后研究。2001-2002年加拿大McGill大学化学系高级访问学者。1990年任南开大学副教授,1995年任教授,1998年任博士研究生导师。曾任南开大学元素有机化学研究所所长、元素有机化学国家重点实验室主任;现任南开大学研究生院副院长。2002年任中国化学会理事及《化学通报》编委。1991年获中国有突出贡献博士学位获得者称号;2000年获中国化学会有机化学专业委员会"杰出有机合成青年化学家"提名奖;2002年获天津市自然科学二等奖;2003年获第七届天津青年科技奖。2004年获科技部国家重点实验室建设先进个人金牛奖。研究领域:1. 过渡金属双核及多核络合物的研究2. 含金属基团的聚合物的设计、合成、结构及性能研究3. 绿色化学4. 第四主族金属有机化学教学及研究成果:在国内外核心刊物上发表研究论文50余篇。参加编写"化工百科全书"等2部专著,主讲研究生课程"金属有机化学"。科研课题包括国家自然科学基金面上基金,科技部国家十五攻关重点项目,教育部基金课题以及多项企业合作项目。
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【期刊论文】水相中Barbier-Prins环化串联一锅法合成四氢吡喃*
李靖, 温梅姣, 唐龙, 常卫星, 李靖**
中国科学 B 辑化学,2004,34(4): 1~5,-0001,():
-1年11月30日
通过对水的用量、催化剂、醛与溴丙烯的比例、反应温度等因素对反应的影响的探索,发现了水相中Barbier-Prins 环化串连的一锅法合成2,4,6-三取代全顺式四氢吡喃的新反应。反应达到了原子利用率高,对环境友好,可在水相中进行反应的目的。
Barbier, 反应, Prins, 环化, 四氢吡喃, 水相, 环境友好
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李靖, Daniel Miguel*, Jing Li, ‡, Dolores Morales, and Víctor Riera Santiago García-Granda
Organometallics 2001, 20, 3063-3069,-0001,():
-1年11月30日
The reaction of [MnRe(CO)6(
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李靖, Jing Li, Daniel Miguel, *, †, M. Dolores Morales, and Victor Riera
Organometallics 1998, 17, 3448-3453,-0001,():
-1年11月30日
Complexes [Mn2(CO)6(µ-S2CPR3)] (R=Cy(1a), Pri (1b)) are reduced with Na[Hg] in THF to afford the anions [Mn2(CO)6(µ-S2CPR3)]2-(2a,b), which give neutral unstable [Mn2(CO)6-(µ-SH){µ-SC(H)PR3}(NH3)] (3a,b) upon protonation with excess NH4PF6. The NH3 ligand of 3a,b is readily replaced by PEt3 to obtain [Mn2(CO)6(µ-SH){µ-SC(H)PR3}(PEt3)] (5a,b) as stable crystalline solids, which have been isolated and characterized. The same reduction/protonation sequence when applied to the dirhenium analogue [Re2(CO)6(µ-S2CPCy3)] (1c) affords stable crystalline [Re2(CO)6(-SH){µ-SC(H)PCy3}(NH3)] (6). An X-ray determination revealed that 6 contains one bridging SH-and the novel ligand Cy3PC(H)S-which is bonded as µ2-η1(S);η2(C,S'), donating 5e to the metals. Both bridging ligands are produced from the cleavage of one C-S bond of the starting S2CPR3 during the reduction/protonation process, which can be regarded globally as hydrogenolysis of the C-S bond. Additionally, the Re-Re bond is also cleaved during the process. As their dimanganese analogues, 6 undergo easy substitution of NH3 by PEt3 to give [Re2(CO)6(µ-SH){µ-SC(H)PCy3}(PEt3)] (7). Comparison of the spectroscopic data indicate that both series of compounds are isostructural, with the only difference being the higher stability of the dirhenium complexes when compared to those of dimanganese.
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李靖, Georgina Barrado, Jing Li, Daniel Miguel, *, Julio A. P
Organometallics 1994, 13, 2330-2336,-0001,():
-1年11月30日
The reaction of [M(CO)3(S2CPR3)Br] (M=Mn, Re) with Co2(CO)8 produces the heterobi-nuclear complexes [MCo(CO)5(μ-S2CPR3)] (2). An X-ray determination of the derivative with M=Mn, and R=Cy [2a, triclinic, space group P1, a=11.074(3) A, b=11.156(3) A, c=11.769(3) A, a=74.64(1)°,β=85.36(1)°, γ=83.44(2)°, Z=2, R=0.042, Rw=0.043] showed the formation of a Mn-Co bond, and the presence of the S2CPR3 ligand coordinated as a η2(S,S') chelate to Mn and as a η3(S,C,S') pseudoallyl to Co. The structure of 2a, and the spectroscopic data of all derivatives 2a-d indicate that the central carbon of the S2CPR3 ligand shows a definite preference for attachment to cobalt rather than to manganese or rhenium and that the reaction produces specifically the compounds with the carbon bonded to the cobalt atom. Although the reactions could be considered as involving the disproportionation of Co2(CO)8 into Co-Ⅰ and CoⅡ, it is noticeable that the direct reaction of the starting [M(CO)3(S2CPRs)Br] with Co(CO)4-gives complexes 2 only for M=Re, but not for M=Mn. The method can be extended to prepare complexes containing Mo-Co and W-Co bonds. Thus, Co2(CO)8 reacts with [M(η3-C3H5)(CO)2(S2-CPR3)Br] (3; M=Mo, W) to produce [MCo(η3-C3H5)(CO)4(μ-S2CPR3)] (4a-d) in moderate yields. An X-ray structure determination of the derivative with M=Mo, R=Cy [4a.CH2CI2, triclinic, space group P1, a=10.301(1) A, b=11.347(7) A, c=15.723(2) A, a=90.08(2)°, β=102.46(4)°, γ,=112.84(1)°, Z=2, R=0.062, Rw=0.070] established the existence of a direct Mo-Co bond, and the presence of the S2CPCy3 ligand bonded as η2(S,S') chelate to Mo and as a η3(S,C,S') pseudoallyl to Co, in the same fashion observed for the structure of the Mn-Co derivative 2a. Again there is a selective formation of a C-Co bond, which indicates a definite preference of the central carbon to bind cobalt rather than molybdenum. In this case, the formal oxidation states are MoI and Co0 and the preference observed is consistent with our previous observations, which can be rationalized assuming that the central carbon of S2CPR3 prefers to bind the metal atom with the lower oxidation state. A common feature ofthe structures of 2a and 4a is the occurrence of a Co(CO)2 fragment which is bonded to a MSCS' ring which donates formally 5 e. In this sense, the molecules of 2a and 4a are isoelectronic to CpCo(CO)2. Some geometric parameters of the structures of 2a and 4a compare well with those in CpCo-(CO)2, suggesting that there is a close analogy between the two types of molecules.
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李靖, Bernardo Alvarez a, Santiago Garcia-Granda lb, Jing Li la, Daniel Miguel, *, la, and Victor Riera a
Organometallics 1994, 13, 16-17,-0001,():
-1年11月30日
The anions [MnM(CO)
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李靖, Yong-Qiang Ma a, Ning Yin a, Jing Li a, *, Qing-Lan Xie a, Daniel Miguel b
Journal of Organometallic Chemistry 689(2004)1949-1955,-0001,():
-1年11月30日
The reaction of homobinuclear rhenium-rhenium complex [Re2(CO)6(l-S2CPCy3)] (1c) with Li[BHEt3] in THF produces anionic 2c which reacts with CS2 affording a new anion 3c, through desulfurization and CS insertion, in a fashion paralel to that of the perviously known Mn-Mn and Mn-Re analogues. Anions 3a-3c undergo allylation and metallation to give neutral products 4a-4k. The structures of [MnRe(CO)6(l-H){l-S(SSnBun3)C=C(PCy3)S}] (4d) and [MnRe(CO)6(l-H){l-S(SC3H5)C=C(PCy3)S}] (4h) have been determined by X-ray diffraction revealing the (OC)3Mn-Re(CO)3 core unit bridged by hydride and the novel S-tributylstannyl-, or (S-allyl)-(tricyclohexylphosphonio)ethenetrithiolate ligands.
Phosphine-carbon disulfide adduct, Binuclear complex, Crystal structure
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【期刊论文】A homodinuclear complex of manganese containing novel ligand, Mn2(CO)6(
李靖, Yong Qiang Ma a, Lei Yu a, Cheng Song Hu a, Xiao Chen a, Jing Li a, *, Hong Gen Wang a, Daniel Miguel b
Journal of Molecular Structure 650(2003)45-48,-0001,():
-1年11月30日
The title complex Mn2(CO)6(
Phosphine-carbon disulfide adduct, Homodinuclear complex, Crystal structure
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【期刊论文】Building of dithiocarbamate and dithiocarbimate ligands within a heterobimetallic core
李靖, Jing Li, a Daniel Miguel, *b Dolores Morales, c V
Dalton Trans., 2003, 3264-3269,-0001,():
-1年11月30日
Heterobinuclear anions [MnRe(CO)6(μ-S)(μ-SCPR3)]2-(2) undergo selective protonation and electrophilic addition of dimethylthiocarbamoyl or isothiocyanate to afford, respectively, neutral [MnRe(CO)6(μ-S2CNMe2)(μ-S2CPR3)] (3) containing μ2-(S,S') dithiocarbamate, or anionic [MnRe(CO)6(μ-SC(S)NR){μ-SC(H)PR3}]-(4) containing μ2-(N,S)-dithiocarbimate. The terminal sulfur in the latter can be methylated with MeI or metallated with [AuCl(p-tolyl)3] to give neutral dithiocarbimato complexes 5 or 6. The structures of 3a (R=Pri), 5a (R=Pri, R=Et), and 5c (R=Pri, R=Ph), have been determined by X-ray crystallography.
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【期刊论文】Synthesis and Reaction of [MnRe(CO)6(μ-SH)(μ-SC(H)PPri3)(PPh3)]
李靖, Yong Qiang MA, Xiao CHEN, Jing LI*, Qing Lan XIE, Hong Gen WANG
Chinese Chemical Letters Vol. 14, No.4, pp 413-416, 2003,-0001,():
-1年11月30日
The synthesis, the crystal structure and the reaction of the hetero-binuclear complex [MnRe(CO)6(μ-SH)(μ-SC(H)PPri 3)(PPh3)] are reported. The results of single crystal X-ray structure analysis showed that the fragments Mn(CO)3 and Re(CO)3 were bridged by SH and SC(H)PPri3. The title complexes can react with BunLi and RX forming complexes MnRe(CO)6(μ-SR)(μ-SC(H)PPri3)(PPh3) (R=Me, CH2CH=CH2, SnBu3n).
Hetero-binuclear complexes,, synthesis,, reaction,, crystal structure.,
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