朱文祥
稀土配位化学,大环配位化学和超分子化学
个性化签名
- 姓名:朱文祥
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学术头衔:
博士生导师
- 职称:-
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学科领域:
无机化学
- 研究兴趣:稀土配位化学,大环配位化学和超分子化学
朱文祥,男,1941年2月10日生,江西永新人。中共党员,教授。1964年7月毕业于北京师范大学化学系。1979年春作为我国首批公派出国进修教师赴英国伦敦大学玛丽皇后学院化学系访问研究。现任化学系博士生导师,校教学指导委员会委员,《北京师范大学学报》编委。北京化学会理事长。中国化学会理事,化学教育委员会副主任,《化学教育》杂志主编,《大学化学》杂志编委,国际杂志《Journal of Science Education》编委等职。朱文祥教授长期从事无机化学教学与科学研究工作,主要研究领域为稀土配位化学,大环配位化学和超分子化学。先后主持和参加国家自然科学基金研究项目4项,北京市自然科学基金项目1项,教育部教改研究项目1项。指导硕士、博士研究生25名。重要著作有《中级无机化学》、《漫话国宝---稀土元素》、《中级无机化学选论》、《配位化学研究方法》、《无机化合物制备手册》;译著有《高等无机化学》、《化学世界导游》、《电子计算机在化学中的应用》等。发表论文80余篇。曾获学校优秀教学成果奖,学校成人教育特等奖,北京市优秀教学成果一等奖和国家级优秀教学成果二等奖以及曾宪梓优秀教师奖等。先后被学校评为模范教师和优秀共产党员。
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成果数
10
朱文祥, 刘茹, 朱文祥*, 张永安, 延玺
化学学报,2001,59(5):553~527,-0001,():
-1年11月30日
合成了未见文献报道的1,10-二氧(4,7,13,16-四氮杂-18-C-6(以下用[18]N4O2代表)的硝酸镧配合物。并在丙酮中培养出{La[18]N4O2(NO3)3}·H2O配合物单晶,用X射线衍射法测定了晶体结构。晶体属三斜晶系,空间群P1,晶胞参数α=1.0690(2)nm,b=1.3608(3)nm,c=0.8230(2)nm;α=103.10(3)℃,β=104.71(3)℃,γ=84.03(3)℃;Z=2,V=1.1265(4)nm3,Dc=1.779g/cm3,μ=1.968mm-1,F(000)=608,R=0.0307,wR=0.0566。冠醚环上的2个氧原子、4个氮原子均参与配位,3个硝酸根也均以双齿形式配位,中心La(Ⅲ)离子的配位数为12,配位多面体为畸变的二十面体,H2O分子存在于配位外界。
镧(, Ⅲ), 配合物,, 氮杂冠醚,, 晶体结构
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【期刊论文】Crystal Structure of Adduct 2-Phenyl-imidazo [4,5-f] 1,10-phenan-throline Methanol
朱文祥, LIN, Hui-Wen a, ZHU, Wen-Xiang*, b
CHINESE JOURNAL OF CHEMISTRY 2003, 21, 1054-1058,-0001,():
-1年11月30日
The structure of the title adduct comprises a phenanthroline derivative 2-phenyl-imidazo [4, 5-f] 1,10-phenanthroline and a methanol. The composition of the crystalline adduct was characterized as C19H12N4
1,, 10-phenanthroline derivative,, crystalline adduct,, crystal structure,, 2-phenyl-imidazo[4,, 5-f] 1,, 10-phenanthroline
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朱文祥, GUO, Qian-Ling a, ZHU, Wen-Xiang*, a, GUO, Rong a, YAN, Xi a, WANG, Ru-Ji b
CHINESE JOURNAL OF CHEMISTRY 2003, 21, 211-215,-0001,():
-1年11月30日
The complex Eu (btfa)3 (phon) (btfa=4,4,4-trifluoro-1-phenyl-1, 3-butanedione, phen=1,10-phenanthroline) has been prepared and characterized by elemental anniysis, IR and UV spectroscopies. The crystal and molecular structures of the complex have been determined by X-ray diffraction analysis. It belongs to the monoclinic crystal system, space group P21/c with a=0.9700(2)nm, b=3.7450(5)nm, c=1.0917(3)nm, β=92.51(2)℃, V=3.962(1) nm3, Z=4, Dc=1.639g/cm3, μ=1.676nm-1, F(000)=1936, R1=0.0388, wR2=0.0775. Structure analysis shows that the europium (Ⅲ) ion is coordinated to six oxygen atoms of β-diketonate anions and two nitrogen atoms of phenanthroline molecule. The coordination polyhedron is an approximate square antiprism.
uropium(, Ⅲ), complex,, benzoyltrifluoroacetone,, 1,, 10-phenanthroline,, crystal structure
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【期刊论文】四氮杂-18-冠-6的锌/铜(Ⅱ)配合物的合成与结构
朱文祥, 郭雪雁, 延玺, 王如骥, 李勇
高等学校化学学报,2002,23(10):1842~1846,-0001,():
-1年11月30日
合成了1,10-二氧-4,7,13,16-四氮杂-18-C-6(以下用L代表)的硝酸锌和硝酸铜(Ⅱ)配合物,配合物CU(L)(NO3)2晶体属正交晶系,Pbca空间群,晶胞参数如下:A=1.5744(6)nm,b=1.2676(4)m,c=1.8983(6)nm,V=3.789(2)nm, Z=8,最终偏离因子R1=0.0431,wR2=0.0904。配合物Zn(L)(NO3)2晶体属正交晶系,Pnna空间群,晶胞参数a=1.61356(10)nm,b=1.32871(11)nm,c=0.86260(5)nm,V=1.8494(2)nm3,Z=4,最终偏离因子R1=0.0718,wR2=0.1950。冠醚环上的4个氮原子和+个氧原子都参与了配位,NO-未参与配位,中心金属离子的配位数为6。红外光谱、1H NMR和EPR谱等研究佐证了上述测定结果。Cu(L)(NO3)2循环伏安实验表明该配合物在-1.0~0V电压范围内,只发生Cu(Ⅱ)→Cu(Ⅰ)的还原反应,而在-1.6~0V电压范围内,发生Cu(Ⅰ)→Cu(0)的反应。
二氧-四氮杂冠醚, 锌/, 铜配合物, 晶体结构
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朱文祥, Qian-Ling Guo a, Wen-Xiang Zhu a, *, Song Gao b, Shu-Lan Ma a, Shu-Jing Dong a, Miao-Qiong Xu a
Inorganic Chemistry Communications 7(2004)467-470,-0001,():
-1年11月30日
X-ray structural determination of the title complex shows it containing a phenoxy and sulfato-bridged Cu(II) tetramer coordinating to fully deprotonated p-sulfonated thiacalix[4]arene with its cavity occupied by a pyridinium cation and forming a 2D coordination polymer. Variable temperature susceptibility measurement reveals an antiferromagnetic coupling of four Cu(II) ions formed.
Crystal structure, 2D Coordination polymer, Copper tetramer, p-Sulfonated thiacalix[4]arene
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朱文祥, Qian-ling Guo, Wen-xiang Zhu*, Shu-lan Ma, Da-qiang Yuan, Shu-jing Dong, Miao-qiong Xu
Journal of Molecular Structure 690(2004)63-68,-0001,():
-1年11月30日
The X-ray crystallographic studies are reported for the water-soluble trivalent lanthanide complexes of the macrocyclic p-sulfonatothiacalix[4]arene [Gd(H2O)6((CH3)2SO)( p-sulfonatothiacalix[4]arene)]
p-Sulfonatothiacalix[4]arene, Trivalent lanthanide complexes, Crystal structure, 2D hydrogen bonded polymer
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【期刊论文】Second-sphere coordination in the complex [Mn(H2O)6]2[thiacalix[4]arene tetrasulfonate]
朱文祥, Qianling Guo, Wenxiang Zhu*, Shujing Dong, Shulan Ma, Xi Yan
Journal of Molecular Structure 650(2003)159-164,-0001,():
-1年11月30日
The title calixarene, dimanganese thiacalix[4]arene tetrasulfonate, was prepared and its crystal structure was determined. [Mn(H2O)6]2[thiacalix[4]arene tetrasulfonate]·0.5H2O crystallizes in the monoclinic system, P2(1)=m space group, with a=13.014(6); b=14.146(9); c=13.184(7)?, β=113.307(10)℃; V=2229(2)?3 and Dc=1.710 gcm-3, Z=2: The title calixarene exists in the solid state as bilayer structure. The hydrophobic organic layer consists of thiacalix[4]arene tetrasulfonate in an up-down fashion, whereas, the hydrophilic inorganic layer consists of hexaaquamanganese (II) which is linked to the former through a second-sphere coordination.
Thiacalix[4]arene, Sulfonate, Crystal structure, Second-sphere coordination, Manganese(, II),
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朱文祥, Qian-Ling Guo, Wen-Xiang Zhu*, Ying-Chun Liu, Da-Qiang Yuan, Jing Zhang, Shu-Lan Ma
Polyhedron 23(2004)2055-2061,-0001,():
-1年11月30日
4,13-Diaza-18-crown-6 is shrouded by two p-sulfonatothiacalix[4]arenes in the presence of trivalent lanthanide ions in two different types of arrangements: (4,13-diaza-18-crown-6){(4,13-diprotodiaza-18-crown-6)
Sulfonatothiacalixarene, Capsules, Diaza-18-crown-6, Lanthanide ions
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朱文祥, Qian-Ling Guo, Wen-Xiang Zhu*, Shu-Lan Ma, Shu-Jing Dong, Miao-Qiong Xu
Polyhedron 23(2004)1461-1466,-0001,():
-1年11月30日
The reaction of tetrasodium p-sulfonatothiacalix[4]arene and transition metal ions (Co2+, Ni2+ and Cu2+) in the presence of 4, 13-diaza-18-crown-6 gives two types of crystalline complex: (4,13-diaza-18-crown-6)2[M(H2O)2+6]{(4,13-diprotodiaza-18-crown-6)
Sulfonatothiacalixarene, Capsules, Diaza-Crown ether, Transition metal ions, Assembly
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朱文祥, Shujing Dong, Wenxiang Zhu, * Daqiang Yuan and Xi Yan
Acta Crystallographica Section C Crystal Structure Communications ISSN 0108-2701,-0001,():
-1年11月30日
A new p-tert-butylthiacalix[4]arene derivative, C72H68N4O4S4·2CH2Cl2, has been synthesized and is comprised of one tetra-p-tert-butyltetrakis (2-cyanobenzyloxy) tetrathiacalix[4]arene and two dichloromethane molecules. The calyx[4]arene molecule is centrosymmetric and adopts an unusual 1, 2-alternate conformation via π-πinteractions between adjacent cyanophenyl rings on the lower rim of the parent thiacalix[4]arene system.
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