薛冬峰
博士 教授 博士生导师
中国科学院长春应用化学研究所 化工学院材料化工系
功能无机材料结晶物理化学;无机材料设计与模拟;无机材料合成方法学
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- 姓名:薛冬峰
- 目前身份:在职研究人员
- 担任导师情况:博士生导师
- 学位:博士
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学术头衔:
博士生导师
- 职称:高级-教授
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学科领域:
无机化学
- 研究兴趣:功能无机材料结晶物理化学;无机材料设计与模拟;无机材料合成方法学
薛冬峰,男,1968年出生于河南省方城县,研究员,博士生导师。2014年12月至今任中国科学院长春应用化学研究所所长助理。2015年5月至今任稀土资源利用国家重点实验室主任。1993年7月毕业于河南大学,获应用化学工学学士学位;1998年7月毕业于中国科学院长春应用化学研究所,获无机化学理学博士学位。此后,分别在德国奥斯纳布吕克大学物理系、加拿大渥太华大学化学系、日本国立材料科学研究所(JSPS)做博士后。2003年8月应聘到大连理工大学工作,被聘任为化工学院材料化工系主任、教授、博士生导师。2011年2月应聘到中国科学院长春应用化学研究所,任研究员、博士生导师。2014-2016连续三年入选Elsevier中国高被引学者榜单。2017年受聘国家新材料产业发展专家咨询委员会委员。
主要从事稀土功能材料研究。提出了结晶生长的化学键合新思想,探索了不同尺度下无机材料在生长过程中的介尺度结晶热力学和动力学,研发了公斤级大尺寸、高质量稀土晶体的稳定快速生长技术。提出了组成元素晶相金属电负性、离子电负性、共价电负性、键电负性标度和溶液相的电负性标度,强化了原子水平上新型无机材料的相组成计算与预测研究。建立了胶体离子超级电容器电极材料新体系,极大提高了电极材料的电化学活性和利用率。在Chem. Soc. Rev., J. Am. Chem. Soc., Adv. Mater., Phys. Rev. Lett.等期刊上发表论文400余篇,论文被他人正面引用5000余次;撰写专著3部、译著1部。曾获1998年中国科学院研究生院长奖学金特别奖、2000年全国优秀博士学位论文、2009年中国建筑材料科学技术奖二等奖、2010年中国颗粒学会青年颗粒学奖、2011年ISFM功能材料进展杰出科学家奖。目前兼任中国稀土学会副理事长,还兼任Science China-Technological Sciences, Materials Research Bulletin,《应用化学》等10余种学术期刊编委。
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590
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成果数
13
【期刊论文】Insulating Tubular BN Sheathing on Semiconducting Nanowires
薛冬峰, Ying-Chun Zhu, * Yoshio Bando, Dong-Feng Xue, Fang-Fang Xu, and Dmitri Golberg
J. AM. CHEM. SOC. 2003, 125, 14226~14227,-0001,():
-1年11月30日
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【期刊论文】Nanocable-Aligned ZnS Tetrapod Nanocrystals
薛冬峰, Ying-Chun Zhu, *, † Yoshio Bando, † Dong-Feng Xue, ‡ and Dmitri Golberg†
J. AM. CHEM. SOC. 2003, 125, 16196~16197,-0001,():
-1年11月30日
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【期刊论文】Oriented Assemblies of ZnS One-Dimensional Nanostructures**
薛冬峰, By Ying-Chun Zhu, * Yoshio Bando, Dong-Feng Xue, and Dmitri Golberg Dr. Y C. Zhu, Prof. Y Bando, Dr. D. Golberg
Adv. Moter, 2004, 16, No.9-10, May 17,-0001,():
-1年11月30日
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【期刊论文】New Boron Nitride Whiskers: Showing Strong Ultraviolet and Visible Light Luminescence
薛冬峰, Ying-Chun Zhu, * Yoshio Bando, Dong-Feng Xue, Takashi Sekiguchi, Dmitri Golberg, Fang-Fang Xu, and Quan-Lin Liu
J. Phys. Chem. B 2004, 108, 6193~6196,-0001,():
-1年11月30日
Boron nitride whiskers with a special structure have been synthesized by a thermal reaction process. The as-prepared BN whiskers have a length of tens of micrometers and a mean diameter of 500 nm. High-resolution TEM analysis shows that the as-prepared BN whiskers can be described as a nanofiber-interweaved network. Infrared and electron energy loss spectra reveal that the BN whiskers are composed of both
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【期刊论文】Novel Self-Assembled MgO Nanosheet and Its Precursors
薛冬峰, Chenglin Yan and Dongfeng Xue*
J. Phys. Chem. B 2005, 109, 12358~12361,-0001,():
-1年11月30日
A novel self-assembled microstructure, nestlike Mg5(CO3)4(OH)2
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【期刊论文】Fabrication of Malachite with a Hierarchical Sphere-like Architecture
薛冬峰, Jiasheng Xu and Dongfeng Xue*
J. Phys. Chem. B 2005, 109, 17157~17161,-0001,():
-1年11月30日
Malachite (Cu2(OH)2CO3) with a hierarchical sphere-like architecture has been successfully synthesized via a simple and mild hydrothermal route in the absence of any external inorganic additives or organic structuredirecting templates. Powder X-ray diffraction, scanning electron microscopy, and Fourier transmission infrared spectrometry are used to characterize various properties of the obtained malachite samples. The hierarchical malachite particles are uniform spheres with a diameter of 10-20
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【期刊论文】Chemical bond analysis of the crystal growth of KDP and ADP
薛冬峰, Dongli Xu, Dongfeng Xue*
Journal of Crystal Growth 286(2006)108~113,-0001,():
-1年11月30日
The bond valence model is employed to calculate the bond strength of constituent chemical bonds formed between growth units in both potassium dihydrogen phosphate (KDP) and ammonium dihydrogen phosphate (ADP) crystals, with the aim to predict and control the crystal shape. After calculating and comparing the relative growth rates of all selected planes, which are related to the crystallographic structure and chemical bond strength, the natural morphology of both KDP and ADP can be conveniently deduced. To check the calculated results, the crystallites of KDP and ADP are grown under different growth conditions; their morphologies accord well with our theoretical calculations. Meanwhile, the influence of ethanol anti-solvent on crystal morphology is microscopically interpreted, which alters the crystal morphology by changing the supersaturation of the growing solution and influencing the bonding process. When ethanol is added into the growing solution, the crystal shape becomes slender.
A1., Crystal morphology, A1., Crystal structure, A1., Crystallites, A1., X-ray diffraction, B1., Phosphates, B2., Nonlinear optic materials
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薛冬峰, Chenglin Yan and Dongfeng Xue*
J. Phys. Chem. B 2006, 110, 1581~1586,-0001,():
-1年11月30日
A novel spontaneous ion replacement route based on the solubility difference as the driving force to synthesize a number of metal oxides has been established. We present a comprehensive study on the ion replacement reaction for chemical synthesis of micro-and nanostructured Mn2O3, ZnO, CuO, CdO, Al2O3, and CaO samples. This novel approach described herein is derived from the solubility difference between two carbonate salts, in which a metal cation can be driven from one liquid phase into another solid phase in the solution system. The resulting metal carbonate salts are initially formed and subsequently calcined to form highly crystallined metal oxides. The variation of pH values, reaction temperature, and reagent shapes can vary the solubility of these two carbonate salts, which thus changes the final morphology of metal oxides. The present work makes a progress to simply and mildly synthesize metal oxides with various morphologies, due to the fact that materials with a desired morphology are a key engineering step toward their shape-dependent chemical and physical properties.
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【期刊论文】The origin of nonlinearity in KTiOPO4
薛冬峰, Dongfeng Xue and Siyuan Zhanga)
Appl. Phys. Lett., Vol. 70, No. 8, 24 February 1997 943~945,-0001,():
-1年11月30日
The origin of nonlinearity in KTiOPO4 was investigated quantitatively from the chemical bond viewpoint. All constituent chemical bonds in this crystal were considered and their contributions to the total linearity and nonlinearity were quantitatively determined. Calculated results agree satisfactorily with experimental data in both signs and numerical values. These results show us that TiO6 groups and P(1)O4 groups have relatively larger linear contributions and the nonlinearity derives from KOx (x58,9) groups and P~2!O4 groups.
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【期刊论文】Chemical Bond Analysis of Nonlinearity of Urea Crystal
薛冬峰, Dongfeng Xue and Siyuan Zhang*
J. Phys. Chem. A 1997, 101, 5547~5550,-0001,():
-1年11月30日
A novel and quantitative study on structure-property relationships has been carried out in urea crystal, based on the dielectric theory of complex crystals and the modified Levine bond charge model, mainly from the chemical bond viewpoint. For the first time, it was treated like this, and the bond parameters and linear and nonlinear characteristics of constituent chemical bonds were presented quantitatively. The theoretical result agrees satisfactorily with the experimental datum and can reasonably explain the nonlinear origin of urea crystal, that is, the C-N bond in the conjugated system of bonds OWCrN-H. At the same time, the novel method should be a useful tool toward the future development of the search for new nonlinear optical (NLO) materials in the organic crystal field.
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