纪顺俊
应用有机化学反应和合成方法学(微波和超声波作用下的水相反应,离子液体反应等绿色化学研究)以及有机光化学和有机小分子光电材料的研究。
个性化签名
- 姓名:纪顺俊
- 目前身份:
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学术头衔:
博士生导师
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学科领域:
有机化学
- 研究兴趣:应用有机化学反应和合成方法学(微波和超声波作用下的水相反应,离子液体反应等绿色化学研究)以及有机光化学和有机小分子光电材料的研究。
纪顺俊,男,1958年11月生,江苏丹阳人,教授、有机化学博士生导师。1980-1984年毕业于苏州大学化学系同年留校工作。1984-1995年曾任苏州大学化学化工学院团委副书记、书记、党总支副书记兼副院长等、1995年自费留学日本,2000年获得日本立教大学大学院有机合成理学博士学位。2000年10月回苏州大学工作。2001-2007年曾任江苏省有机合成重点实验室主任、江苏省有机化学国家级重点学科负责人、化学化工学院院长等职。现为国家自然科学基金委员会项目通讯评审专家、江苏省化学化工学会理事、有机化学专业委员会副主任,2007年11月任苏州市人事局长、党组书记、市委编办主任。 在J. Am. Chem. Soc.; Org. Lett.; Chem. Commun.; Synlett, Tetrahedron /Tetrahedron Lett.;等国际权威刊物上发表高质量论文100余篇,被他人引用超过300余次。主持完成国家自然科学基金2项,目前在研主持国家自然科学基金1项,江苏省自然科学基金2项和江苏高校重大项目1项。课题组目前已获得江苏省优秀博士两篇和江苏省优秀硕士论文两篇。获得苏州大学科学技术进步二等奖一次;苏州大学周氏优异奖一次;苏州大学科研大陆奖一次;苏州大学苏鑫科研奖一次;苏州市科技论文一等奖、二等奖各二次。
主要研究方向为应用有机化学反应和合成方法学(微波和超声波作用下的水相反应,离子液体反应等绿色化学研究)以及有机光化学和有机小分子光电材料的研究。
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457
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成果数
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【期刊论文】Highly Enantioselective Allylation of Aldehydes Catalyzed by Indium(III)-PYBOX Complex
纪顺俊, Jun Lu, †, ‡ Shun-Jun Ji, *, ‡ Yong-Chua Teo, † and Teck-Peng Loh *, †, ‡
Org. Lett., Vol. 7, No. 1, 2005,-0001,():
-1年11月30日
A chiral indium(III)-PYBOX complex prepared from indium triflate and chiral PYBOX has been discovered to effect high enantioselectivities in the addition of allyltributyl stannane to aldehydes. The allylation of a variety of aromatic, r,
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【期刊论文】Ultrasound-promoted alkynylation of ethynylbenzene to ketones under solvent-free condition
纪顺俊, Shun-Jun Ji *, Zhi-Liang Shen, Da-Gong Gu, Xiao-Ying Huang
Ultrasonics Sonochemistry 12(2005)161-163,-0001,():
-1年11月30日
This paper described alkynylation of ethynylbenzene to ketones catalyzed by potassium tert-butoxide under solvent-free conditions in the presence of ultrasound irradiation.
Ethynylbenzene, Propargylic alcohol, Solvent-free, Ultrasound
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纪顺俊, Zhi-Liang Shen, a, b Shun-Jun Ji b, * and Teck-Peng Loh a, b, *
Tetrahedron Letters 46(2005)507-508,-0001,():
-1年11月30日
Mukaiyama aldol and Mukaiyama–Michael reactions can proceed smoothly in the presence of a catalytic amount of DBU (20% mmol), to afford the corresponding products in moderate to good yields. This solvent- and metal-free approach provides an environmentally friendly procedure for Mukaiyama reactions.
Mukaiyama reaction, DBU, Organic catalyst, Solvent-free condition, Metal-free.,
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纪顺俊, Jun Lu, ac Shun-Jun Ji *a and Teck-Peng Loh *ab
COMMUNICATION Chem. Commun., 2005, 2345-2347,-0001,():
-1年11月30日
In the presence of chiral catalytic complexes prepared from In(OTf)3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94% ee) and good yields (68-89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.
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纪顺俊, Zhi-Liang Shen, b Shun-Jun Ji b, * and Teck Peng Loh a, b, *
Tetrahedron Letters 46(2005)3137-3139,-0001,():
-1年11月30日
Ionic liquid [omim][PF6] has been demonstrated as an efficient and environmentally friendly reaction media as well as a promoter for the cyanosilylation of aldehydes under mild conditions. In addition, the recovered ionic liquid could be reused for subsequent runs with only a gradual decrease in activity.
Ionic liquid, [omim][PF6], TMSCN, Cyanosilylation, Cyanohydrins, Recycle.,
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纪顺俊, Jin-Ming Yang a, b, Shun-Jun Ji a, *, Da-Gong Gu a, Zhi-Liang Shen a, Shun-Yi Wang a
Journal of Organometallic Chemistry 690(2005)2989-2995,-0001,():
-1年11月30日
A facile Michael addition of ferrocenylenones with aliphatic amines under ultrasound irradiation in the absence of solvent and catalyst at room temperature can afford 1-ferrocenyl-3-amino carbonyl compounds rapidly in high yields, which is also efficient in the aza-Michael reaction of other a,b-unsaturated carbonyl compounds such as chalcone, carboxylic ester, etc. However, aromatic amines do not undergo the conjugate addition at all, and the reactions under existing methods do not proceed or take place in low yield after a long reaction time. Apart from experimental simplicity, generality and selectivity, the advantages of this methodology are the rapid, environmentally benign and less expensive processes, which will contribute to the progress of green chemistry.
Michael addition, Ferrocene,, amine, b-amino carbonyl compound, Ultrasound, Solvent-free
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纪顺俊, Jun Lu, a, c, Shun-Jun Ji, *, Yong-Chua Teoc and Teck-Peng Loha, b
Tetrahedron Letters 46(2005)7435-7437,-0001,():
-1年11月30日
An indium complex of chiral PYBOX was applied in the catalytic asymmetric allylation of ketones in the ionic liquid. It was found that this chiral indium complex was strong enough to promote the reaction of ketones with allyltributylstannane smoothly. The products were obtained in moderate to high enantioselectivities, and the chiral catalyst immobilized in the ionic liquid could be reused with comparable enantioselectivities and yields.
PYBOX, Indium, Asymmetric allylation, Ketone, Ionic liquid.,
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纪顺俊, Xiao-Fei Zeng, Shun-Jun Ji* and Shun-Yi Wang
Tetrahedron 61(2005)10235-10241,-0001,():
-1年11月30日
The reaction of indole with (1H-indol-3-yl)(alkyl) methanol was catalyzed efficiently by ceric ammonium nitrate under ultrasonic irradiation to afford the unsymmetrical bis(indolyl)alkane in good to excellent yields.
Indoles, CAN, Ultrasound irradiation, Unsymmetrical bis(, indolyl), methanes.,
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纪顺俊, Zhi-Liang Shen, Shun-Jun Ji, * Shun-YiWang and Xiao-Fei Zeng
Tetrahedron 61(2005)10552-10558,-0001,():
-1年11月30日
A convenient, efficient, and practical method for the synthesis of b-indolylketones via a condensation of indole, aromatic aldehydes, and deoxybenzoin under ultrasonic irradiation was described. It provided a novel base-promoted approach for the one-pot synthesis of bindolylketones.
Indole, β-Indolylketone, One-pot synthesis, Ultrasound.,
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纪顺俊, Shun-Jun Ji, a, b, *, Shun-Yi Wang, b Yong Zhang a, b and Teck-Peng Loh b, c
Tetrahedron 60(2004)2051-2055,-0001,():
-1年11月30日
Efficient electrophilic substitution reactions of indoles with various aromatic aldehydes were carried out using a catalytic amount of I2 under solvent-free conditions to afford the corresponding bis(indolyl)methanes in excellent yields.
Solvent-free, Iodine, Indoles, Aldehydes, Bis(, indolyl), methanes.,
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