董育斌
博士 教授
山东师范大学 化学化工与材料科学学院
多年从事金属有机化学、分子材料及配位聚合物化学方面的研究工作,在1)基于“T-型”建筑基元的配位聚合物的超分子异构化研究;2)含异种金属中心的配位聚合物;3)金属-π键驱动的金属有机配位聚合物;4)基于弯折型有机分子的自组装体系的设计、合成与物化性质的研究等方面做了系统的研究工作。
个性化签名
- 姓名:董育斌
- 目前身份:在职研究人员
- 担任导师情况:
- 学位:博士
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学术头衔:
博士生导师
- 职称:高级-教授
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学科领域:
有机化学
- 研究兴趣:多年从事金属有机化学、分子材料及配位聚合物化学方面的研究工作,在1)基于“T-型”建筑基元的配位聚合物的超分子异构化研究;2)含异种金属中心的配位聚合物;3)金属-π键驱动的金属有机配位聚合物;4)基于弯折型有机分子的自组装体系的设计、合成与物化性质的研究等方面做了系统的研究工作。
董育斌,男,1965年出生,1987年于山东师范大学化学系获学士学位,1993年于山东大学化学系获硕士学位,1996年于南开大学化学院获博士学位,1996-2000年在香港大学(RA)和美国USC (Research Assistant Prof.)从事博士后研究工作,2000-至今山东师范大学化学院教授。
入选国家百千万人才工程,是国家级“有突出贡献中青年专家”,泰山学者特聘教授(第二管理服务期),享受国务院政府特殊津贴专家,山东省首届优秀研究生指导教师,ESI全球化学领域前1%科学家。曾获全国先进工作者,全国优秀科技工作者等荣誉称号。曾获国家科技进步二等奖,山东省自然科学一等奖,山东省科技进步一等奖,山东省教学成果一等奖和山东省研究生教育省级教学成果一等奖等。
主要从事超分子组装化学和金属有机化学的教学和研究工作。在配位作用驱动的组装体(金属-有机框架(MOFs)、共价有机骨架材料(COFs)、配位聚合物(CPs)和离散型分子容器)的合成、结构及其性质的研究方面形成了自己的特色。在J. Am. Chem. Soc., Angew. Chem., Chem. Mater., Chem. Commun., Inorg. Chem., Organometallics等国际有重要影响的学术刊物上发表研究论文100余篇,引用5800余次,H指数44。申请专利19件,授权14件。所培养的研究生有1人获全国百优博士学位论文提名奖,16人获研究生国家奖学金,7人获山东省优秀博士和硕士学位论文奖。
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董育斌, Yu-Bin Dong, * Hai-Ying Wang, Jian-Ping Ma, Da-Zhong Shen, and Ru-Qi Huang
Inorg. Chem. 2005, 44, 4679-4692,-0001,():
-1年11月30日
Two new bent bis(cyanophenyl)oxadiazole ligands, 2,5-bis(4-cyanophenyl)-1,3,4-oxadiazole (L7) and 2,5-bis(3-cyanophenyl)-1,3,4-oxadiazole (L8), were synthesized. The coordination chemistry of these ligands with various Ag(I) salts has been investigated. Seven new coordination polymers, namely, {[Ag(L7)(H2O)]ClO4}n (1) (triclinic, P1h, a=9.342(4) Å, b=9.889(4) Å, c=10.512(4) Å, R=68.978(6)°, β=78.217(6)°, ç=81.851(7)°, Z=2), {[Ag(L7)]SO3CF3}n (2) (monoclinic, P21/n, a=7.559(2) Å, b=23.739(6) Å, c=10.426(3) Å, β=108.071(4)°, Z=4), {[Ag(L8)]BF4β0.5(C6H6)βH2O}n(3) (triclinic, P1h, a=7.498(3) Å, b=10.649(4) Å, c=13.673(5) Å, R=98.602(5)°, β=100.004(5)°, ç )110.232(5)°, Z=2), {[Ag(L8)SbF6]βH2O}n (4) (triclinic, P1h, a=8.2621(9) Å, b=10.6127(12) Å, c=13.3685(15) Å, R=98.012(2)°, β=106.259(2)°, ç=112.362(2)°, Z=2), {[Ag2(L8)2(SO3CF3)]βH2O}n (5) (triclinic, P1h, a=10.713(4) Å, b=13.449(5) Å, c=15.423(5) Å, R) 65.908(5)°, β=74.231(5)°, ç=83.255(5)°, Z=2), {[Ag2(L8)(C6H6)(ClO4)]βClO4}n (6) (monoclinic, P21/n, a=6.9681(17) Å, b=20.627(5) Å, c=17.437(4) Å, β=95.880(4)°, Z=4), and {[Ag2(L8)(H2PO4)2]}n (7) (triclinic, P1h, a=7.956(2) Å, b=9.938(3) Å, c=14.242(4) Å, R=106.191(4)°, β=97.322(4)°, ç=107.392(4)°, Z=1), were obtained by the combination of L7 and L8 with Ag(I) salts in a benzene/methylene chloride mixedsolvent system and fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. In addition, the luminescence and electrical conductance properties of compounds 1-6 and the host-guest chemistry of compound 3 were investigated.
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董育斌, Yu-Bin Dong, * Yan Geng, Jian-Ping Ma, and Ru-Qi Huang
Inorg. Chem. 2005, 44, 1693-1703,-0001,():
-1年11月30日
One new conjugated symmetric fulvene ligand L1 and two new unsymmetric fulvene ligands L2 and L3 were synthesized. Five new supramolecular complexes, namely Ag2(L1)3(SO3CF3)3 (1) (1, monoclinic, P21/c; a=12.702(3) Å, b=26.118(7) Å, c=13.998(4) Å, β=96.063(4)°, Z=4), [Ag(L1)]ClO4 (2) (monoclinic, C2/c; a=17.363(2) Å, b=13.2794(18) Å, c=13.4884(18) Å, β=100.292(2)°, Z=8), [Ag(L1)(C6H6)SbF6]β0.5C6H6βH2O (3) (monoclinic, P21/c; a=6.8839(11) Å, b=20.242(3) Å, c=18.934(3) Å, β=91.994(3)°, Z=4), Ag(L2)(SO3CF3) (4) (triclinic, P1h; a=8.629(3) Å, b=10.915(3) Å, c=11.178(3) Å,R)100.978(4)°, β=91.994(3)°, ç=105.652(4)°, Z=2), and Ag(L3)(H2O)(SO3CF3) (5) (triclinic, P1h; a=8.914(5) Å, b=10.809(6) Å, c=11.283(6) Å, R )69.255(8)°, β=87.163(9)°, ç=84.993(8)°, Z=2) were obtained through self-assembly based on these three new fulvene ligands in a benzene/toluene mixed-solvent system. Compounds 1-5 have been fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The results indicate that the coordination chemistry of new fulvene ligands is versatile. They can adopt either cis- or trans-conformation to bind soft acid Ag(I) ion through not only the terminal -CN and furan functional groups but also the fulvene carbon atoms into organometallic coordination polymers or discrete complexes. In addition, the luminescent properties of L1-L3 and their Ag(I) complexes were investigated preliminarily in EtOH and solid state.
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董育斌, Yu-Bin Dong, * Peng Wang, and Ru-Qi Huang; Mark D. Smith
Inorg. Chem. 2004, 43, 4727-4739,-0001,():
-1年11月30日
Three new rigid conjugated fulvene ligands L1-L3 were synthesized. L1 and L3 have been prepared by an aroylation reaction of cyclohexyl-substituted cyclopentadienyl anions. L2 was prepared by the reaction of L1 with PhNHNH2 in hot enthanol. Six new coordination polymers, namely [Ag(C25H20N2O2)(ClO4)]β3.5C6H6 (1), [Ag2(í-C31H24N4)(è2-C6H6)(H2O)](ClO4)2β(C6H6)β(H2O)0.5 (3), [Ag(C31H24N4)]SbF6βsolvate (4), [Ag(C31H24N4)](SbF6)2β2C6H6βCH2Cl2 (5), [Ag-(C25H20N2O2)2]SbF6 (6), and [Ag(C25H20N2O2)2]SbF6 (7), and one seven-membered cobaltacycle-containing complex, namely Co(C25H20N2O2)2(C2H5OH)2 (2), were obtained through self-assembly based on these three new fulvene lignads. L2-L3 and compounds 1-7 have been fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The results indicate that the coordination chemistry of new fulvene ligands is versatile. They can bind metal ions not only through the terminal N-donors and fulvene carbon atoms into organometallic coordination polymers but also through the two chelating carbonyl groups into unusual sevenmembered metallo-ring supramolecular complexes. In the solid state, ligands L1-L3 are luminescent. A blue-shift in the emission was observed between the free ligand L1 and the one incorporated into Co(II)-containing complex 2, and a red-shift in the emission was observed between the free ligand L3 and the one incorporated into Ag(I)-containing polymeric ompounds 6 and 7.
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【期刊论文】Novel CpAg(I)-Containing Organometallic Coordination Polymers Generated from Fulvene Ligands
董育斌, Yu-Bin Dong, * Guo-Xia Jin, Xia Zhao, Bo Tang, and Ru-Qi Huang; Mark D. Smith, K. E. Stitzer, and Hans-Conrad zur Loye*
Organometallics 2004, 23, 1604-1609,-0001,():
-1年11月30日
Two new fulvene ligands, L1 and L2, have been synthesized by an aroylation reaction of the cyclopentadienyl anion. The coordination chemistry of L1 and L2 was investigated. Two novel CpAg(I)-containing polymeric compounds, 1 ([Ag4(L1)2(í-H2O)2(SO3CF3)4]β(í-bis-è1-C6H6))βH2O) and 2 ([Ag2(L2)(H2O)(SO3CF3)2]β0.5(C6H6)), have been synthesized. Compounds 1 and 2 have been fully characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The solid state structure of 1 features a macro-ring-containing one-dimensional chain motif. The solid state structure of 2 features a one-dimensional doublechain motif. These double chains are further cross-linked to each other via CpAg(SO3CF3)2-AgCp (AgβββAg contact of 4.215(15) Å) linkage into a novel 2-D network with large cavities (effective cross-section of ca. 21 9 Å), in which the benzene guest molecules are located.
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董育斌, Yu-Bin Dong, *a Xia Zhao, a Bo Tang, a Huai-You Wang, a Ru-Qi Huang, a Mark D. Smithb and Hans-Conrad zur Loyeb
Chem. Commun., 2004, 220-221,-0001,():
-1年11月30日
Two novel organic–inorganic hybrid coordination polymers were synthesized based on a new multidentate Schiff-base ligand and Ag(I) salts
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董育斌, Yu-Bin Dong, * a, b Jian-Ping Ma, a Guo-Xia Jin, a Ru-Qi Huang a and Mark D. Smith c
Dalton Trans., 2003, 4324-4330,-0001,():
-1年11月30日
One new fulvene-type ligand 1 was synthesized successfully by aroylation reaction of substituted cyclopentadienyl anions. The coordination chemistry of fulvene ligands 1 and 2 were investigated. The study demonstrated that these fulvene-type ligands could be used as bidentate or chelating ligands to coordinate transition metal ions into coordination polymers or supramolecular complexes. Two novel one-dimensional Ag(1)2–fulvene coordination polymers, namely [Ag(1)2(PF6)] C6H6 and [Ag(1)2(SbF6)] 2C7H8, consisting of an Ag2(ligand)2 unit and two M(II) (M=Co(II) and Mn(II)) complexes, namely Co(1)2 2C2H5OH and Mn(2)2 2C2H5OH, with unusual seven-membered metallo-ring units were synthesized successfully. In the solid state, complexes 5 and 6 adopt a novel hydrogen-bonded one-dimensional chain motif
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董育斌, Yu-Bin Dong, * Jun-Yan Cheng, and Ru-Qi Huang; Mark D. Smith and Hans-Conrad zur Loye
Inorganic Chemistry, Vol. 42, No.18, 2003,-0001,():
-1年11月30日
The coordination chemistry of the oxadiazole-containing rigid bidentate ligands 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L1), 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (L2), and 2,5-bis(3-aminophenyl)-1,3,4-oxadiazole (L3) with inorganic Ag(I) salts has been investigated. Four new coordination polymers (1, 2, 3, and 5) and one new bimetallic macrocyclic supramolecular complex (4) were synthesized from solution reactions of L1-L3 with inorganic Ag(I) salts, respectively. Compounds {[Ag(L1)]SbF6}n (1) (1, monoclinic, P21/c, a=6.6846(4) Å, b=27.1113(15) Å, c=8.6802(5) Å, β=94.1080(10)°, Z=4) and {[Ag(L1)]PF6}n (2) (2, monoclinic, P21/c, a=6.6753(3) Å, b=27.2824(14) Å, c=8.2932(4) Å, β=94.6030(10)°, Z=4) were obtained from the reactions of L1 with AgSbF6 and AgPF6 in a CH2Cl2/CH3OH mixed solvent system, respectively. Compounds 1 and 2 are isostructural and feature a novel two-dimensional zeolite-like net with two different individual rings. {[Ag(L2)]SbF6}n (3) (3, monoclinic, P21/c, a=5.5677(3) Å, b=17.3378(9) Å, c=15.6640(8) Å, β=94.4100(10)°, Z=2) and [Ag2(L2)2](SbF6)2 (4) (4, triclinic, P1h, a=8.7221(5) Å, b=9.2008(6) Å, c=10.7686(7) Å, R=70.6270(10)°, β=75.7670(10)°, ç=73.7560(10)°, Z=1) were obtained from one-pot reaction of L2 with AgSbF6 in a CH2Cl2/CH3OH mixed solvent system. Compound 3 features a one-dimensional chain pattern, while compound 4 adopts a novel bimetallic macrocyclic structural motif which consists of Ag2(L2)2 ringlike units (crystallographic dimensions, 8.06 ´ 7.42 Å2). {[Ag(L3)]SO3CF3}n (5) is generated from L3 and AgSO3CF3 in a CH2Cl2/CH3OH mixed solvent system and crystallizes in the unusual space group Pbcn, with a=9.8861(5) Å, b=20.2580(10) Å, c=17.5517(8) Å, Z=8. It adopts novel two-dimensional sheets that are cross-linked to each other by strong interlayer N-HβββO hydrogen bonding interactions into a novel H-bonded three-dimensional network.
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董育斌, Yu-Bin Dong a, ∗, Jian-Ping Ma a, Mark D. Smithb, Ru-Qi Huang a, Bo Tanga, Dian-Shun Guo a, Jin-Shan Wang a, Hans-Conrad zur Loye b
Solid State Sciences 5(2003)601-610,-0001,():
-1年11月30日
Three new Cu(II) coordination polymers have been prepared using Cu(II) salts in combination with 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (L2). The compounds were characterized by single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In the solid state, all three new polymeric compounds 1–3 (1: monoclinic, P2/c, a=10.0956(11) Å, b=6.8710(7) Å, c=18.6152(19) Å, β=97.270(2)◦, V=1280.9(2) Å3, Z=2; 2: monoclinic, P21/c, a=9.2275(5) Å, b=16.0479(9) Å, c=18.3403(3) Å, β=91.1260(10)◦, V=2715.4(3) Å3, Z=4; 3: triclinic, P-1, a=6.9932(7) Å, b=11.5777(12) Å, c=12.5291(13) Å, α=109.401(2)◦, β=103.922(2)◦, γ=95.316(2)◦, V=912.06 Å3, Z=2) feature novel one-dimensional single or double-sinusoidal chain motifs with different repeat periods, which result from the different conformations adopted by the L2 ligand.
Coordination polymers, (, 1,, 3,, 4), -Oxadiazole-containing ligands, Copper
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董育斌, Yu-Bin Dong a, ∗, Jun-Yan Cheng a, Jian-Ping Ma a, Huai-You Wang a, Ru-Qi Huang a, Dian-Shun Guo a, Mark D. Smith b
Solid State Sciences 5(2003)1177-1186,-0001,():
-1年11月30日
"Three new one-dimensional coordination polymers have been prepared using Hg(II), Ag(I) and Zn(II) inorganic salts in combination with 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (L6). The compounds were characterized by single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. In the solid state, compounds 1 and 3 (1: monoclinic, P21/n, a=5.5373(3) Å, b=16.7839(9) Å, c=6.8120(9) Å, β= 92.8610(10)◦, V=1560.52(15) Å3, Z=4; 3: monoclinic, P21/n, a=7.2958(4) Å, b=11.7214(6) Å, c=16.3979(9) Å, β= 101.1150(10)◦, V=1375.99(13) Å3, Z=4) feature novel one-dimensional helical chain motif. Compound 2, however, (2: monoclinic, P21/c, a=5.5506(4) Å, b=16.5895(12) Å, c=16.6871(11) Å, β= 95.424(2)◦, V=1529.70(19) Å3, Z=4) exhibits one-dimensional zigzag chain motif, which result from the different conformations adopted by the L6 ligand and also the different metal coordination geometry. The luminescent properties of three new compounds were investigated in the solid state."
Coordination polymers, (, 1,, 3,, 4), -Oxadiazole-containing ligands, Self-assembly
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