王纪孝
1.功能性高分子,尤其是导电聚合物;2.电化学。
个性化签名
- 姓名:王纪孝
- 目前身份:
- 担任导师情况:
- 学位:
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学术头衔:
博士生导师
- 职称:-
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学科领域:
化学工程基础学科
- 研究兴趣:1.功能性高分子,尤其是导电聚合物;2.电化学。
王纪孝,男,研究员,博导
学习与工作简历:
2000,10- 在天津大学化学工程研究所工作,主要从事于导电聚合物纳米材料的基础和应用研究;
1998,8-2000,10:在天津大学化学工程研究所从事于博士后研究;
1995,9-1998,7: 在南开大学高分子化学研究所攻读高分子化学与物理专业博士学位;
1989,7-1995,9: 在承德石油高等专科学校化工系工作,从事于教学、科研和开发工作;
1986,9-1989,7: 在中国地质科学院研究生部攻读分析化学硕士学位;
1982,8-1986,7: 在中国地质大学应用化学系学习,获岩矿分析学士学位。
主要研究方向
1. 功能性高分子,尤其是导电聚合物
2. 电化学
课题成果:
共参加完成国家、省市等科研课题24项,被授权的专利共6项。
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主页访问
1322
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关注数
0
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成果阅读
238
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成果数
6
【期刊论文】Electrocatalytic reduction of nitrate at polypyrrole modified electrode
王纪孝, Xiuling Zhang a, b, Jixiao Wang a, ∗, Zhi Wang a, Shichang Wang a
Synthetic Metals 155 (2005) 95-99,-0001,():
-1年11月30日
Polypyrrole (PPy) nanowire modified electrode was prepared and its electrocatalytic behavior towards nitrate reduction was characterized.The electrode surfaces were investigated by scanning electron microscopy (SEM) and energy-dispersive X-ray analysis (EDX). The electrocatalyticactivity of modified graphite electrode was compared with graphite, copper (Cu) and platinum (Pt) electrode. The nitrite concentrationproduced at PPy modified electrode is lower than that at any other electrodes, and its changing tendency is opposite to any other electrodes. ThePPy nanowire modified electrodes were further modified by electrodeposition of Cu. The results show that the produced nitrite concentrationgets higher with the increase of Cu content. The primary experimental results show that the modified electrode has promise use in the removeof nitrate from water.
Electrocatalytic, Polypyrrole nanowires, Nitrate reduction, Chemical modified electrode
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39浏览
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王纪孝, Yun Tian, Jixiao Wang∗, Zhi Wang, Shichang Wang
Sensors and Actuators B 104 (2005) 23-28,-0001,():
-1年11月30日
In this paper, the electrochemical solid-phase extraction (EC-SPE) and amperometric determination of nitrite with polypyrrole (PPy)nanowire modified electrode was reported. The PPy nanowire modified electrode was prepared by template-free method in a mixture ofsodium carbonate and sodium bicarbonate aqueous solution and then conditioned in 0.10M perchlorate acid for 24 h. EC-SPE (preconcentration)of nitrite ions was conducted under the condition of applied potential 0.800V for 300 s. The electroreduction of nitrite wasconducted under the condition of −0.200V for 100 s in the solution of 0.50M H2SO4. The length of nanowires, the temperature and thepH of the test solution, the EC-SPE potential and time have significant effects on the corresponding current. Under a certain condition, therelationship between nitrite concentration and corresponding current density is in good linearity. The determination sensitivity may be variedaccording to the modification parameters. Under the experimental condition, the highest corresponding sensitivity is 55.84 mA/M cm2,and may be further improved by modification the electrode with longer polypyrrole nanowires.
Solid-phase extraction, Amperometric, Polypyrrole, Nanowires, Nitrite
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59浏览
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206下载
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【期刊论文】Electroreduction of nitrite at an electrode modifiedwith polypyrrole nanowires
王纪孝, Yun Tian, Jixiao Wang∗, Zhi Wang, Shichang Wang
Synthetic Metals 143 (2004) 309-313,-0001,():
-1年11月30日
In this paper, the electrochemical behavior of polypyrrole nanowire modified electrode is described. The modified electrode has very goodactivity toward nitrite electroreduction. The electroreduction current is linearly dependent on the concentration of nitrite. The experimentalparameters such as thickness of polypyrrole film, pH, and temperature of the test solution, and scan rate which have effects on the reductioncurrent were examined. The result shows that the electroreduction current increases with the increasing of the polypyrrole film thickness,acidity of electrolyte solution, temperature, and scan rate. The good linearity between the electroreduction current and the concentrationof nitrite makes it possible to determine nitrite concentration accurately in the range of 2.28 × 10−4 to 0.020 M.
Polypyrrole, Chemically modified electrode, Nitrite, Nanowires
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245下载
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【期刊论文】The application of polypyrrole fibrils in hydrogen evolution reaction
王纪孝, Xiaoping Mo, Jixiao Wang∗, Zhi Wang, Shichang Wang
Synthetic Metals 142 (2004) 217-221,-0001,():
-1年11月30日
The behavior of the polypyrrole (PPy) fibrils modified electrode during hydrogen evolution process is reported. The experimental resultsshow that the hydrogen evolution current density could be significantly increased on the PPy fibrils modified electrode. The hydrogenevolution current density on the modified electrode increases with PPy fibrils getting longer. The hydrogen evolution current density onfibrillar PPy modified electrode is higher than that on electrode modified with PPy with cauliflower form. Redoping PPy fibrils with metalcomplex could further increase the hydrogen evolution current density.
Hydrogen evolution reaction, Polypyrrole fibril
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【期刊论文】Potentiometric pH responses of fibrillar polypyrrole modified electrodes
王纪孝, Xiaoping Mo, Jixiao Wang∗, Zhi Wang, Shichang Wang
Sensors and Actuators B 96 (2003) 533-536,-0001,():
-1年11月30日
The potentiometric pH responses of novel fibrillar polypyrrole modified electrodes were studied. The effects of the film thickness and thescan rate were examined. The results show that the film thickness has little effect on the potentiometric response for the one-dimensionalgrowth pattern of polypyrrole. This makes it easy to obtain electrodes with the same potentiometric pH response slope. The scan rateinfluences the potentiometric pH response. The highest response slope is 53.0 mV/pH, which was measured on the electrode prepared at ascan rate of 25 mV/s.
Potentiometry, Polypyrrole, Fibrillar morphology, pH response
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99下载
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【期刊论文】Electrochemical synthesis of polypyrrole nanowireson composite electrode
王纪孝, Dongtao Ge, Jixiao Wang*, Zhi Wang, Shichang Wang
Synthetic Metals 132 (2002) 93-95,-0001,():
-1年11月30日
Polypyrrole nanowires growing with two-dimensional instantaneous nucleation and one-dimensional growth pattern were realized ongraphite/paraffin composite electrode in phosphate buffer solution.
Conducting material, Electrochemistry, Nanostructures, Polymers, Polypyrrole
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31浏览
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146下载
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