钱林茂
纳米摩擦学的基础理论及应用研究
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- 姓名:钱林茂
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学术头衔:
博士生导师, 教育部“新世纪优秀人才支持计划”入选者
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学科领域:
机械工程
- 研究兴趣:纳米摩擦学的基础理论及应用研究
钱林茂,教授,男,1971年6月生,清华大学本科、博士,现为西南交通大学教授,博士生导师。曾于1999年11月至2001年10月访问法国高等师范大学,2001年11月至2002年12月访问香港科技大学。十余年以来一直从事纳米摩擦学的基础理论及应用研究,在微观摩擦与粘着机理、原子力/摩擦力显微镜针尖的原位修饰、相变相关的微观变形和磨损机制、纳米级流体膜的失效机理、纳米尺度下链状分子摩擦力的起源等方面有坚实的理论基础和丰富的研究经验,并取得了多项有重要理论意义和应用价值的研究成果。发表学术论文35篇,其中近五年在Applied Physics Letters和Langmuir等国际学术期刊发表论文21篇,被SCI收录18篇,所发表论文被SCI他人引用80次,单篇论文最高被SCI他人引用30次。科研成果分别获中国高校科技进步一等奖(自然科学类)和国家教委科技进步二等奖。曾参与自然科学基金项目“塑性流体力学与润滑失效分析的研究”(19672034)和自然科学基金重大项目“纳米摩擦学的理论与应用基础研究”(59735110)等多个项目的研究工作,主持国家自然科学基金项目(50305029) 和四川省青年科技基金项目(04ZQ026-004) 等科研课题,入选首批教育部“新世纪优秀人才支持计划”。
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16
【期刊论文】Fretting wear behavior of superelastic nickel titanium shape memory alloy
钱林茂, L. Qian a, Q. Sun b and Z. Zhou a, *
Tribology Letters, Vol. 18, No.4, April 2005,-0001,():
-1年11月30日
The fretting behavior of superelastic nickel titanium (NiTi) shape memory alloy was studied at various displacement amplitudes on a serve-hydraulic dynamic test machine. The results showed that the superelastic properties of the material played a key role in the observed excellent fretting behavior of NiTi alloy. Due to the low phase transition stress (only 1/4 the value of its plastic ield stress) and the large recoverable phase transition strain (5%) of NiTi, the friction force of NiTi/GCr15 stainless steel pair is smaller than the value of GCr15/GCr15 pair and at the same time the Rabinowicz wear coefficient of NiTi plate is about 1/9 the value of GCr15 plate under the same fretting conditions. For NiTi/GCr15 pair, even NiTi has a much lower hardness than GCr15, the superelastic NiTi alloy exhibits superior fretting wear property than GCr15 steel. It was found that the weak ploughing was the main wear mechanism of NiTi alloy in the partial slip regime. While in the mixed regime and gross slip regime, the wear of NiTi was mainly caused by the abrasive wear of the GCr15 debris in the three-body wear mode.
fretting wear,, nickel titanium,, shape memory alloy,, superelasticity,, reversible phase transition
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钱林茂, Linmao Qian a, Fang Tian b and Xudong Xiao*, b
Tribology Letters, Vol. 15, No.3, October 2003,-0001,():
-1年11月30日
Using friction force microscopy (FFM) under controlled environments, we have systematically investigated the humidity effect on the frictional properties of two important classes of self-assembled monolayers (SAMs), i.e., N-octadecyltrimethoxysilane (OTE,CH3(CH2)17Si(OCH3)3) on SiO2 (OTE/SiO2); and N-alkanethiols on Au (111), together with their respective substrates. Experimental results show that both OTE and alkylthiol SAMs can decrease the friction force between a Si3N4 atomic force microscope (AFM) tip and substrates. The nearly humidity-independent friction of the two kinds of SAMs indicates that these SAMs are ideal lubricants in applications of micro-electro-mechanical systems (MEMS) under different environments. The humidity dependence-as the humidity increases, the friction first increases and then decreases-of the two substrates, SiO2 and Au (111), can be explained by the adsorption of water. The decrease in the friction at high humidity is attributed to the low viscosity in the multilayers of water, while the increase in the friction at low humidity can be explained by the high viscosity between the water monolayer and the surfaces (AFM tip and sample), possibly due to the confinement effects. The effect of modification of the AFM tip with alkanethiol molecules on the humidity dependence of Au (111) friction has also been investigated.
humidity,, self-assembled monolayers (, SAMs), ,, atomic force microscope (, AFM),
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钱林茂, 雒建斌, 刘姗, 温诗铸
自然科学进展,2000,1(20):89~94,-0001,():
-1年11月30日
采用光干涉法相对光强原理对点接触中心区进行了润滑膜厚度测量,该方法在垂直方向的分辨率可达O.5nm,水平方向可达1μm,讨论了膜厚与压力,速度和润滑油粘度之刘的关系,观察和分析了流体润滑膜的失效现象。实验结果表明如果接触压力足够小或者润滑油粘度足够高,即使在一个很低的速度下也能清晰地观察到流体动压润滑效应。当压力增至某一定值,在膜厚-速度曲线上可观察到一个转辑点,当速度降到此点以下时,润滑膜厚度将很快减小到几个分子层厚,此时,润滑膜不再具有流体润滑特征,即流体润滑膜失效,失效点会出现在不同的速度和压力下。要使接触区在较高的压力下形成流体膜就必须加更高的速度或使用更大粘魔的润滑油。最后建立了失效点的压力、速度和润滑油粘度之间的关系。
纳米润滑膜 失效 薄膜润滑 弹流润滑 边界润滑
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钱林茂, Linmao Qian a) and Xudong Xiao b)Qingping Sun and Tongxi Yu
Appl. Phys. Lett., Vol. 84, No.7, 16 February 2004,-0001,():
-1年11月30日
We have studied the behavior of microwear and hardness of a superelastic nickel-titanium alloy using a triboindenter at various temperatures. Wear resistance was found to anomalously decrease with an increase in hardness. The observations are analyzed based on simple contact theory which suggests that the increase of hardness with the temperature is mainly due to an increase in phase transition stress, while the decrease of wear resistance with the temperature is due to an increase of the austenite elastic modulus and a decrease of the amount of phase transition that can be recovered.
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【期刊论文】The experimental rules of mica as a reference sample of AFM/FFM measurement
钱林茂, QIAN Linmao, LUO Jianbin, WEN Shiwu & XIAO Xudong
Chinese Science Bulletin Vol. 46 No.1 January 2001,-0001,():
-1年11月30日
For the friction measurements with AFM/FFM, usually the relative values of friction signal can be obtained. In order to compare the micro-tribological properties of different samples, mica is often used as an reference sample for friction measurement. However, due to the friction force of new cleaved mica surface is unstable, it is urged to systematically investigate the tribological properties of mica to design the experimental rules of the reference sample mica for friction measurements. Experimental results show that the friction of mica varies with the cleaving time, humidity and surface state of tip. The friction measured with different tips on mica varies in the range of
mica,, friction force,, AFM/, FFM.,
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【期刊论文】Thermally activated lubrication with alkanes: The effect of chain length
钱林茂, L.-M. Qian, , G. Luengo(*) and E. Perez
Europhys. Lett., 61 (2), pp. 268-274 (2003),-0001,():
-1年11月30日
Friction forces measurements between smooth surfaces across two layers of linear alkanes over five decades of speeds are presented. A maximum friction dissipation is observed at a characteristic speed. This behaviour is described by a new approach: the formation and destruction of molecular bridges between confined alkane layers. These bridges which interdigitate between the layers exhibit a thermally activated resistance to shear. An analytical model involving activation barriers accounts for the overall behaviour of the speed dependence of the forces over four decades. This first simple semi-quantitative description sheds new light on the subtle mechanisms of friction at the nanoscale level and shows how the molecular length influences the tribological properties of the liquid.
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【期刊论文】Tetrahedral Onsager Crosses for Solubility Improvement and Crystallization Bypass
钱林茂, Isabelle Aujard, †, Jean-Pierre Baltaze, ‡, Jean-Bernard Baudin, Emmanuelle Cogné, Fabien Ferrage, Ludovic Jullien, *, Eric Perez, §, Valéry Prévost, Lin Mao Qian, §and Odile Ruel†
J. Am. Chem. Soc. 2001, 123, 8177-8188,-0001,():
-1年11月30日
Pure organic molecules exhibiting a suitable concave rigid shape are expected to give porous glasses in the solid state. Such a feature opens new opportunities to avoid crystallization and to improve molecular solubility in relation to the high internal energy of these solid phases. To quantitatively explore the latter strategy, a series of rigid tetrahedral conjugated molecules nC and the corresponding models nR have been synthesized. Related to the present purpose, several properties have been investigated using UV absorption, steady-state fluorescence emission, differential scanning calorimetry, 1H NMR translational self-diffusion, magic angle spinning 13C NMR, and multiple-beam interferometry experiments. The present tetrahedral crosses are up to 8 orders of magnitude more soluble than the corresponding model compounds after normalization to the same molecular length. In addition, they give concentrated monomeric solutions that can be used to cover surfaces with homogeneous films whose thickness goes down to the nanometer range. Such attractive features make cross-like molecular architectures promising for many applications.
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【期刊论文】Dynamic Friction by Polymer/Surfactant Mixtures Adsorbed on Surfaces
钱林茂, Linmao Qian, † Magali Charlot, and Eric Perez* Gustavo Luengo, * Anne Potter, and Colette Cazeneuve
J. Phys. Chem. B 2004, 108, 18608-18614,-0001,():
-1年11月30日
A cationic polyelectrolyte was adsorbed on mica from highly concentrated solutions. The friction and surface force behaviors of the adsorbed layers in aqueous media were studied using a new homemade surface force apparatus (SFA). The long-range repulsions produced by the pure cationic polymer at low salt concentration indicate that the chains are in an extended conformation. The addition of anionic surfactant or of salt condenses the cationic polymer chains as evidenced by the much shorter range of the repulsions. These forces are, for both conformations, a combination of steric and double-layer forces. During sliding, the friction forces produced by the adsorbed layers increase monotonically with the load. A strong dependence of these forces on the sliding speed is noticeable for the extended conformations, while the dependence vanishes in the coiled conformations. This study shows the important role of the conformational state of adsorbed polymer chains on their tribological properties.
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【期刊论文】Investigation of Humidity-Dependent Capillary Force
钱林茂, Xudong Xiao* and Linmao Qian
Langmuir 2000, 16, 8153-8158,-0001,():
-1年11月30日
Due to the strong capillary condensation, the adhesion force between a Si3N4 atomic force microscope (AFM) tip and silicon oxide was observed to first increase and then decrease with an increase of humidity. In contrast, due to weak capillary condensation, the adhesion force between the AFM tip and the N-octadecyltrimethoxysilane (OTE,CH3(CH2)17Si(OCH2CH3)3) self-assembled monolayer (SAM) was found to be almost independent of humidity. It was found that the formulation commonly used for acroscopic objects fails to explain our data. Using an accurate formulation and an assumed tip shape, we can explain the observed decrease of adhesion for SiO2 at high humidity as being due to the decreased capillary pressure force when the dimension of the meniscus becomes omparable with the tip size. However, theobserved late onset of adhesion of SiO2 cannot be understood within the framework of the classical continuum theory. We attribute this late onset to the properties of an ultrathin water film at molecular thickness. The new formulation predicts a vanishing water meniscus between the AFM tip and OTE over the entire humidity range and can also fully account for the humidity-independent adhesion results for OTE.
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【期刊论文】Tip in Situ Chemical Modification and Its Effects on Tribological Measurements
钱林茂, Linmao Qian and Xudong Xiao*Shizhu Wen
Langmuir, Vol. 16, No.2, 2000, 662-670,-0001,():
-1年11月30日
In this paper, we present our experimental results on the process of the in situ chemical modification of the silicon nitride atomic force microscopy/frictional force microscopy tip by n-octadecyltrimethoxysilane (OTE)/mica, OTE/SiO2, and SiO2. The modified tips have different friction and adhesion properties against mica reference samples compared to those before modification. The resultant tip modification depends not only on OTE self-assembled monolayer (SAM) but also on the substrates the OTE SAM is prepared on. In the case of OTE/mica, the friction of the modified tip against mica reference is greatly reduced; in the case of OTE/SiO2, the friction of the modified tip against mica reference is greatly increased. It is surprising that bare SiO2 can also chemically modify the Si3N4 tip to increase the friction against mica reference. In the case of OTE modification, it was found that the tips could be cleaned by repetitive friction scans on mica. However, a tip modified by SiO2 cannot be mechanically cleaned. Moreover, it was found that humidity and load could also affect the tip chemical modification. Ourresults are important for interpreting tribological data since the actual contact chemistry was often overlooked in the atomic force microscopy experiments in the past.
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