曹化强
低维纳米材料合成及纳米器件研究
个性化签名
- 姓名:曹化强
- 目前身份:
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学术头衔:
博士生导师, 教育部“新世纪优秀人才支持计划”入选者
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学科领域:
无机化学
- 研究兴趣:低维纳米材料合成及纳米器件研究
曹化强,理学博士,1965年7月出生于安徽省合肥市。1984.9-1988.7安徽师范大学化学系(获理学学士学位);1988.9-1994.7中国科学院合肥分院工作;1994.9-1997.7中国科学技术大学材料科学与工程系(获理学硕士学位),从事无机陶瓷膜及超细粉研究;1997.9-1999.1中国科学院大连化学物理研究所工作,从事固体氧化物燃料电池研究;1999.3-2001.6南京大学化学系(获理学博士学位),从事一维纳米材料及磁学性质研究;2001.9-2003.8清华大学化学系(博士后),从事一维纳米材料及光学性质研究;2003.8 -至今 清华大学化学系(副研究员),从事低维纳米材料合成及纳米器件研究。2002年获“南京大学优秀博士学位论文”奖,2003年获“全国优秀博士学位论文”奖,2004年获“新世纪优秀人才支持计划”资助及“2004年度教育部提名国家科学技术奖-自然科学一等奖”(第三完成人)。
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2663
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成果阅读
308
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成果数
8
曹化强, Xia Changrong*, Cao Huaqiang, Wang Hong, Yang pinghua, Meng Guangyao, Peng Dingkun
Journal of Membrane Science 162(1999)181-188,-0001,():
-1年11月30日
Yttria stabilized zirconia (YSZ) polymeric sols were synthesized by controlled hydrolysis and condensation of zirconium tetra-n-propoxide. Yttrium nitrate was added before hydrolysis as the source of yttria. Acetylacetone was used as chelating ligand to modify the reaction rate of zirconium alkoxide. The dependence of YSZ sol formation as well as gelation time was investigated experimentally on the contents of acetylacetone, n-propanol (solvent) and water for hydrolysis. With a stable sol, YSZ membranes were prepared on porous a-alumina supports by a dip-coating process. The membranes were characterized by scanning electron microscopy and gas permeability testing. Unsupported YSZ membranes were also prepared with the same sol, and were investigated with isothermal nitrogen adsorption/desorption porosimetry and X-ray diffraction. The results show that YSZ membranes with nanosize pores were successfully prepared by the sol
YSZ, Sol-gel, Ceramic membrane, YSZ sol, Controlled hydrolysis
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【期刊论文】An array of iron nanowires encapsulated in polyaniline nanotubules and its magnetic behavior
曹化强, Huaqiang Cao, a, c, Zheng Xu, *a, Dong Sheng, d, Jianming Hong, Hai Sangb, and Youwei Du b
J. Mater. Chem., 2001, 11, 958-960,-0001,():
-1年11月30日
An array of iron nanowires within polyaniline nanotubules was obtained using a two-step template synthesis. First, an array of polyaniline nanotubules was synthesized in an alumina template, and then it was used as a "second-order template" for electrodeposition of iron within the polyaniline nanotubules. The polyaniline envelope may protect the iron nanowires against the corrosive atmosphere. The composite nanostructure was characterized by EDX, XRD and SEM and its magnetic properties were measured by VSM. Coercive forces of the array of iron nanowires encapsulated within polyaniline range from about 119 to 210 Oe with an increase from 0 to 90
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【期刊论文】Sol-gel synthesis of an array of C70 single crystal nanowires in a porous alumina template
曹化强, Huaqiang Cao, a, Zheng Xu, *a, Xianwen Wei, Xiang Ma b, and Ziling Xue c
Chem. Commun., 2001, 541-542,-0001,():
-1年11月30日
An ordered array of C70 single crystal nanowires was prepared by a sol-gel template method which is composed of three steps: generation of the C70 sol; deposition of C70 sol particles in the pores of the alumina membrane; and annealing of the resulting C70 composite in an argon atmosphere.
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【期刊论文】Room-temperature ultraviolet-emitting In2O3 nanowires
曹化强, Huaqiang Cao, a), Xianqing Qiu, Yu Liang, and Qiming Zhu a), Meijuan Zhao
Downloaded 26 Dec 2003 to 166. 111. 28. 89.,-0001,():
-1年11月30日
Semiconductor In2O3 nanowires embedded in an alumina template were fabricated using template technology. Scanning electron microscopy and transmission electron microscopy observations show that the In2O3 nanowire single crystal has an average diameter around 80nm and a length over 10mm. A strong photoluminescence (PL) emission with a peak at 398nm (3.12eV in photon energy) was detected upon excitation of the In2O3 nanowires at 274nm (4.53eV in photon energy) and 305nm (4.08eV in photon energy) under room temperature. The observed UV PL emission is attributed to the near band edge emission.
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【期刊论文】Array of nickel nanowires enveloped in polyaniline nanotubules and its magnetic behavior
曹化强, Huaqiang Cao, Chenyang Tie, and Zheng Xu a), Jianming Hong, Hai Sang
Downloaded 26 Dec 2003 to 166. 111. 28. 89.,-0001,():
-1年11月30日
An array of nickel nanowires enveloped in polyaniline nanotubules was prepared by the "econd-order-template" method. As the first step, an array of the polyaniline nanotubules was synthesized in the pores of an alumina membrane, then nickel nanowires were fabricated by electrochemical deposition of the nickel into the polyaniline nanotubules. The composite nanostructure was characterized by x-ray powder diffraction, and scanning electron micrography. Its magnetic properties were measured by a vibrating sample magnetometer. The coercivity and remanence are of high anisotropy with a maximum at θ=90°(parallel to the nanowires).
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曹化强, By Huaqiang Cao, Yan Xu, Jianming Hong, Huibiao Liu, Gui Yin, Baolong Li, Chenyang Tie, and Zheng Xu*
Adv. Mater. 2001, 13, No.18, September 14,-0001,():
-1年11月30日
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曹化强, By Huaqiang Cao, Zheng Xu, *, Hai Sang, Dong Sheng, and Chenyang Tie
Adv. Mater. 2001, 13, No.2, January 16,-0001,():
-1年11月30日
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曹化强, By Huaqiang Cao, *, Xianqing Qiu, Bin Luo, Yu Liang, Yuhui Zhang, Ruiqin Tan, Meijuan Zhao, and Qiming Zhu*
Adv. Funct, Mater. 2004, 14, No.3, March,-0001,():
-1年11月30日
This paper reports the synthesis of tetragonal zirconia nanowires using template method An as-prepared sample was characterized by scanning and transmission electron microscopy. It was found that the as-prepared materials were tetragonal zirconia nanowires with average diameters of ca. 80nm and length of over 10um. The Raman spectrum showed peaks at 120, 461 and 629cm1, which are attributed to the Eg, Eg, and B1g phonon modes of the tetragonal zirconia structure, respectively. The UV-vis absorption spectrum showed an absorption peak at 232 5nm (5.33eV in photon energy) Photoluminescence (PL) spectra of zirconia nanowires showed a strong emission peak at ca 388nm at room temperature, which is attributed to the ionized oxygen vacancy in the zirconia nanowires system.
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