代斌
等离子体化学、有机合成和天然产物化学方面的研究
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- 姓名:代斌
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学术头衔:
博士生导师, 教育部“新世纪优秀人才支持计划”入选者
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学科领域:
应用化学(具体应用入有关学科)
- 研究兴趣:等离子体化学、有机合成和天然产物化学方面的研究
代斌,男,1969年10月生,四川渠县人,大连理工大学应用化学专业博士,石河子大学教授、化学化工学院副院长、应用化学研究中心主任、生物化工实验室常务副主任、化工系主任,石河子大学学报(自然科学版)第3届编委,《国家重点新产品计划》网上评估(评审)专家,石河子市新产品标准评审专家,2004年入选教育部新世纪优秀人才支持计划,石河子大学青年骨干教师。主要从事等离子体化学、有机合成和天然产物化学方面的研究。主持、承担和参与各级各类项目20余项,发表学术论文50余篇。
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代斌, 代斌**, 张秀玲, 张琳, 宫为民, 何仁, 陆文琪, 邓新禄
中国科学(B辑):2001,32(2):174~177,-0001,():
-1年11月30日
在常温常压下,研究了脉冲放电等离子体及其协同催化剂强化CH。氢化偶联反应。结果表明:脉冲电晕等离子体条件下,甲烷中引入氢气可以实现偶联,而且随着氢气引入量的增加甲烷的转化率以及C2收率增大,积碳减少;脉冲电压和重复频率影响CH4的转化;引入Ni/γAl2O3催化剂后可改善产物C2烃的分布,等离子体法制备的Ni/γAl2O3催化剂性能优于化学法制备的Ni/γAl2O3催化剂,开辟了一条甲烷偶联新技术路线。
甲烷, 氢气, 偶联, 脉冲放电等离子体, Ni/, γAl2O3
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【期刊论文】Study on the hydrogenation coupling of methane
代斌, DAI Bin, , ZHANG Xiuling, ZHANG Lin, GONG Weimin, HE Ren, LU Wenqi, & DENG Xinlu
SCIENCE IN CHINA (Series B) April 2001 Vol. 44 No.2,-0001,():
-1年11月30日
At atmospheric pressure and ambient temperature, the hydrogenation coupling of methane was studied by using pulse corona plasma and its synergism with catalyst. The results showed that (í) under pulse corona plasma, the coupling of methane could be fulfilled by the addition of hydrogen, and with the increase of the amount of hydrogen, the conversion of methane and the yield of C2 hydrocarbon increased, and the deposit of carbon decreased; (íí) the conversion of methane was affected by pulse voltage and repeated frequency; (ííí) in the system, the addition of Ni/g-Al2O3 could improve the distribution of C2 hydrocarbon; (íν) the activity of Ni/g-Al2O3 prepared by cold plasma was better than that by chemical methods. The experiment opened up a new technical route of the coupling of methane.
methane, hydrogenation coupling, pulse corona plasma, Ni/, g-Al2O3.,
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【期刊论文】Study on the Methane Coupling under Pulse Corona Plasma by Using CO2 as Oxidant
代斌, DAI Bin, , ZHANG Xiu-ling, GONG Wei-min, HE Ren
Plasma Science & Techology, 2000, 2 (6): 577~580,-0001,():
-1年11月30日
In this paper, the conversion of CO2/CH4 by using pulse corona plasma was studied at atmospheric pressure and ambient temperature. The effects of ratio of CO2/CH4, pulse voltage and repeated frequency of plasma discharge were first studied in the system.
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代斌, Xiuling Zhang a, b, Bin Dai a, Aimin Zhu a, Weimin Gong a, Changhou Liu a
Catalysis Today 72 (2002) 223-227,-0001,():
-1年11月30日
The pulse corona plasma has been used as an activation method for reaction of methane and carbon dioxide, the product was C2 hydrocarbons and by-products were CO and H2. Methane conversion and the yield of C2 hydrocarbons were affected by the carbon dioxide concentration in the feed. The conversion of methane increased with increasing carbon dioxide concentration in the feed whereas the yield of C2 hydrocarbons decreased. The synergism of La2O3/Al2O3 and plasma gave methane conversion of 24.9% and C2 hydrocarbons yield of 18.1% were obtained at the power input of plasmawas 30W. The distribution of C2 hydrocarbons changed by using Pd-La2O3/Al2O3 catalyst, the major C2 product was ethylene.
Pulse corona plasma, Catalyst, Methane, Carbon dioxide
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代斌, 宫为民, 张秀玲, 张琳, 何仁
高等学校化学学报, 2001, 22 817-820,-0001,():
-1年11月30日
常温常压下,利用脉冲电晕等离子体与NiC2Al2O3催化剂协同作用CO2加氢转化生成甲烷,考察了催化剂担载量、放电参数、工艺参数等对反应的影响,并探讨了其反应机理。结果表明, 在等离子体与催化剂协同作用下,CO2加氢生成CH4,CO2 转化率在催化剂一定担载量范围内随担载量的增加而增加;脉冲电压峰值、重复频率、进气方式、空速等对反应有重要影响;相同条件下,等离子体2催化法优于化学催化法。
等离子体催化剂, 二氧化碳甲烷化, 脉冲放电等离子体, NiC2Al2O3
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代斌, , 张秀玲, 宫为民, 何仁
石油化工,2002,31(2):141~144,-0001,():
-1年11月30日
等离子体, 催化, 甲烷转化
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【期刊论文】Effects of Hydrogen on the Methane Coupling under Non-equilibrium Plasma
代斌, DAI Bin, , ZHANG Xiu-ling, GONG Wei-min, HE Ren
Plasma Science & Technology, 2001, 3 (1): 637~639,-0001,():
-1年11月30日
In this paper, hydrogen is first utilized in the study on methane coupling under non-equilibrium plasma. Results indicate that the addition of hydrogen is beneficial to the methane coupling so as to increase the conversion rate of methane and the yield of Ca hydrocarbon with a gradual increase in the addition of hydrogen in a certain range of proportionality. This conclusion explores a new route of hydrogenated methane coupling.
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代斌, Xiu Ling ZHANG, , Wei Min GONG*, Bin DAI, Chang Hou LIU
Chinese Chemical Letters Vol. 13, No.2, pp 175-176, 2002,-0001,():
-1年11月30日
In the reaction of methane and carbon dioxide to C2 hydrocarbons under nonequilibrium plasma, methane conversion was decreased, but selectivity of C2 hydrocarbons was increased when using La2O3/Al2O3 as catalyst. So the yield of C2 hydrocarbons was higher than using plasma alone. The synergism of La2O3/ -Al2O3 and plasma gave methane conversion of 24.9% and C2 yield of 18.1%. The distribution of C2 hydrocarbons changed when Pd-La2O3/-Al2O3 was used as catalyst, the major C2 product was ethylene.
Non-equilibrium plasma, catalyst, methane, carbon dioxide
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代斌, 宫为民, 张秀玲, 朱爱民, 张报安
中国环境科学,1999,19(5):410~412,-0001,():
-1年11月30日
研究了在常温常压下,脉冲电晕等离子体对温室气体CO2的活化与转化。分别考察了反应气体流速、脉冲电压峰值、放电频率对纯CO2转化的影响。结果表明,CO2主要分解为CO和O2,另有少量积碳和臭氧产生;随着反应气体流速的增加,CO2转化率、CO产率和选择性降低;随着脉冲电压峰值和放电频率的升高。CO2转化率、CO产率增大,CO选择性降低。
脉冲电晕等离子体, CO2转化, 常压, 非平衡等离子体
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【期刊论文】Methane Coupling over Cu/SiO2 Catalyst under a Plasma
代斌, DAI Bin, , GONG Weimin, ZHANG Xiulimg, HE Ren
Chinese Journal of Catalysis, 2002, 23 (4): 297~398,-0001,():
-1年11月30日
lnethane coupling,, copper,, supported catalyst,, hydrogen,, pulsed corona plaslna
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