徐明厚
从事煤的燃烧理论、燃烧污染物生成机理和先进燃烧技术的研究与开发工作。
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- 姓名:徐明厚
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学术头衔:
博士生导师, “973”、“863”首席科学家, 教育部“新世纪优秀人才支持计划”入选者
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学科领域:
动力机械工程
- 研究兴趣:从事煤的燃烧理论、燃烧污染物生成机理和先进燃烧技术的研究与开发工作。
徐明厚,男,1966年6月生,中共党员,煤燃烧国家重点实验室主任、教授、博导。1986年毕业于华中工学院动力工程系,1989年和1992年在华中理工大学分别获工学硕士、博士学位,毕业以后留校任教。1994年被聘任为副教授,1997年11月至2000年1月在葡萄牙里斯本工业大学做博士后研究,其中1999年7月至1999年9月在澳大利亚悉尼大学机械系高级访问学者。1999年6月被聘任为教授,2001年被聘任为博士生导师。现任中国高等教育学会工程热物理委员会理事,中国电力教育协会能源动力工程学科教学委员会委员、能源动力工程学科教学委员会电力环境保护学科分委员会副主任,“热科学与技术”杂志编委。为国际燃烧学会、美国化学学会会员。2002年入选教育部“跨世纪人才”计划。徐明厚教授多年来主要从事煤的燃烧理论、燃烧污染物生成机理和先进燃烧技术的研究与开发工作,在大型锅炉先进燃烧技术,特别是电站四角燃烧锅炉煤粉燃烧器;大型四角切圆燃烧方式锅炉烟温和汽温偏差;燃烧系统的空气动力特性与燃烧特性、辐射特性;燃烧中NOx的生成机理及其简化反应模型;燃烧过程中痕量元素生成的化学动力学机理;煤燃烧过程中有机污染物的生成;煤中无机组分在燃烧过程中的物理化学变化过程、成灰和沉积机理等方面取得了创新性成绩。其中“煤燃烧过程中非主量组分的变化行为和氧化亚氮生成规律的理论描述”获得2002年度国家自然科学二等奖;“湍流及多相反应流介观模型的新进展” 2003年获得教育部提名国家科学技术奖自然科学一等奖;“煤燃烧过程中矿物质变化行为的理论描述及数值模拟” 2000年获得湖北省自然科学一等奖;此外,获得省部级自然科学二等奖1项、科技进步二等奖和三等奖各3项;合作出版专著3部;在国际学术刊物发表论文20余篇,SCI、EI收录论文50篇。承担并完成包括国家 “七五” 及“八五”科技攻关、国家攀登计划、国家基金项目、企事业单位委托项目等在内的科研与工程课题数十项;目前主持“973”项目课题“燃烧源一次颗粒物的生成、成核与生长机制”,3项国家自然科学基金(包括国家杰出青年科学基金),中葡、中美国际合作等10余项科研项目。
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徐明厚
,-0001,():
-1年11月30日
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徐明厚, Minghou Xu, ''*, Xiuguang He, , J. L. T. Azevedo, and M. G. Carvalho
Int. J. Energy Res. 2000; 24: 1161-1169,-0001,():
-1年11月30日
The efficient use of pulverized coal is crucial to the utility industries. The use of computational fluid dynamics (CFD)-based numerical models has an important role in the design of new boiler furnaces or in retrofitting situations. The results of CFD simulations can be used to better understand the complex processes occurring within the boiler furnace. The use of these results to support boiler operation and training of operators requires that the CFD models can be easily accessed and the results are easily analysed. This paper discusses two ways to simulate the heat transfer process in boiler furnaces. The method directly applying CFD results is employed, in which the grid for solving the energy equation is the same as the flow grid in the CFD simulation while radiation heat transfer is solved in another relatively coarse grid. Comparison of the prediction results between CFD and Heat Transfer code (Simple model) is performed under boiler full load (100%) with one side wall fouling, as well as for different boiler loads (100, 98 and 95 per cent boiler full load, respectively). Finally, the flexible use of the results of CFD and the simple model for pulverized coal-fired boilers is presented. To facilitate the use of the system, a user-friendly interface was developed which enables the user to manipulate new calculations and to view results, namely performing'what-if' analysis. Copyright ~ 2000 John Wiley & Sons, Ltd.
pulverized coal combustion, heat transfer, CFD
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【期刊论文】SIMPLIFICATION OF THE MECHANISM OF Nox FORMATION IN A CH4/AIR COMBUSTION SYSTEM
徐明厚, MINGHOU XU*, YAOGUO FAN AND JIANWEI YUAN
Int. J. Energy Res. 23: 1267-1276 (1999),-0001,():
-1年11月30日
The mechanism of detailed chemical reactions in combustion is very complicated, especially when the formation of pollutant such as NOx is considered. Based on Glarborg's and Bilger's full model (Glarborg P. et al., Combustion and Flame, 65, 177; (1986), Bilger R. W., Starner S.H., Kee, R.J., Combustion and Flame, 80, 135 (1990)), a simplified model of the mechanism of NOx formation in a CH4/Air system is presented. Sensitivity calculation and eigenvalue-eigenvector analysis fprincipal component analysis (Vajda S., Valko P., Turanyi T., Int. J. Chemicaf Kinetics, 17: 55 (1985)) are used in the model. Compared with the conventional methods of simplification of chemical reaction mechanisms such as quasi. steady-state approximation, the eigenvalue-eigenvector analysis can indicate the important reactions efficiently without providing any balance hypothesis. The new model consists of only 15 elementary reactions, which is simpler than the full model composing 39 reactions. The deviations in NOx concentration and other major species between the simplified and the full model are rather small over a wide range of fuel-air ratio.Meanwhile, the calculated NOx concentrations by the simplified model are in quite good agreement with Bartok's experimental data (Bartok W. et al., AICHE Symp. Ser. 126 (1972)), especially in the fuel-lean region.
nitrogen oxides, eigenvalue-eigenvector analysis, modelling
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【期刊论文】A SIMPLIFIED FUEL-NOx MODEL BASED ON REGRESSION ANALYSIS
徐明厚, MINGHOU XU*, YAOGUO FAN, JIANWEI YUAN, CHANGDONG SHENG AND HONG YAO
Int. J. Energy Res., 23, 157-168 (1999),-0001,():
-1年11月30日
The mechanism of detailed chemical reactions in combustion is very complicated, especially when the formation of a pollutant such as NOx is considered. Based on regression analysis, a simplified fuel-NOx model is developed for premixed flame. The new model iS available for a wider range of temeperature and fuel-air ratios compared with De Soete's (1975) fuel NO model. The reduction CHi species on NO iS considered so that the model can be used in both fuel-lean and fuel-rich combustion systems. After a great simulation of a one-dimensional premixed flame system using Miller and Bowman'S (1989, Prog. Energy Combust. Sci., 15, 287) detailed elementary reaction model, the calculation of all the reaction rates is presented based on regression analysis.Copyright
nitrogen oxides, regression analysis, modelling
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【期刊论文】Modelling of the combustion process and NOx emission in a utility boiler
徐明厚, M. Xu a, *, J.L.T. Azevedo b, M.G. Carvalho b
Fuel 79(2000)1611-1619,-0001,():
-1年11月30日
This paper presents numerical simulation of the flow and combustion process in the furnace of a pulverized coal fired utility boiler of 350 MWe with 24 swirl burners installed at the furnace front wall. Five different cases with 100, 95, 85, 70 and 50% boiler full load are simulated. The comparison between the simulation and the plant data is stressed in this study. The heat flux to furnace walls between the measured values and the calculation results is compared. It is found that increasing the load leads to consistent variations in the properties presented and the exception is observed for the full load case where the predicted exit gas temperature is lower than the 95% one and the total heat to the boiler walls is smaller. This might be due to the fact of considering a linear scaling of the input parameters between the 70% and 100% load. The increase of the air flow rate led as expected to a reduction of the furnace outlet temperature and to a small decrease in NOx emissions. It shows that the NOx model used shows a higher sensitivity to temperature than to oxygen level in the furnace. The model used considered the De Soete mechanism for the nitrogen from volatiles and the contribution of char was considered in a similar way. The agreement for all cases except the one of 50% boiler load between the calculation results with the plant data validates the models and algorithm employed in the computation. The furnace performance under different boiler loads is predicted and compared in order to meet the requirements of NOx abatement and avoiding some negative side effects on the furnace. q2000 Elsevier Science Ltd. All rights reserved.
Modelling, NOx emission, Utility boiler
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【期刊论文】Status of trace element emission in a coal combustion process: a review
徐明厚, Minghou Xu a, *, Rong Yan b, , Chuguang Zheng a, Yu Qiao a, Jun Han a, Changdong Sheng a
Fuel Processing Technology 85(2003)215-237,-0001,():
-1年11月30日
Several important aspects are described in this paper. The occurrences of trace elements (TEs) in coal are introduced. Four main groups of trace element content level, say, >50, 10-50, 1-10 and < 1 ppm, can be drawn. Trace elements partitioning in emission streams; enrichment in submicron particles; vaporization and emission in flue gas; and the mobility and leaching behavior of trace elements in coal and combustion waste are summarized. The mechanisms of trace element transformation during combustion are illustrated as following: the vaporized metals at high temperature near the combustion flame will subsequently nucleate or condense at a lower temperature downstream. These metals form a suspended aerosol along with particles. The conversion of vaporized components into various solid and/or liquid forms is the key factor influencing the final trace elements' transformation/partitioning behavior. Finally, current trace element emission control technologies are briefly introduced. To control trace elements in particle phase, electrostatic precipitators and fabric filters are mainly used. To control trace elements in vapor phase, spray dryer absorbers, wet scrubbers, condensing wet scrubbers, wet scrubbers and solid sorbent injection should mainly be used. Research needs are identified and potentially promising research topics on trace elements emission are proposed as following: (1) trace element speciation and enrichment in coal and coal ash. (2) Trace elements partitioning in combustion process. (3) Mechanisms of transformation and control technologies for easily vaporized TEs during combustion.
Trace elements, Coal combustion, Trace element emission
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徐明厚, Minghou Xu, *, † Changdong Sheng, and Jianwei Yuan
Energy & Fuels 2000, 14, 533-538,-0001,():
-1年11月30日
Problems commonly occur when the coal type and/or the load are changed in utility boilers. To solve these problems, a new pulverized coal burner, namely, a burner with continuously variable concentrations of coal dust by using a set of blades, is developed in this study. Gas-solid twophase flow downstream of the burner was measured by three-dimensional particle dynamics anemometer (3D PDA). The results show that the particle concentration biased degree of the burner can be continuously adjusted between 1 and 3 by changing the angle between the blades and the primary air flow, over a range of 0-20
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【期刊论文】Modelling and Mechanism of NOx Emissions Under FueI Staging During Combustion
徐明厚, M. XU*, Y. FAN and J. YUAN
Combust. Sci. and Tech., 1998, Vol. 133, PP. 377-394,-0001,():
-1年11月30日
Staged combustion has been accepted as an effective way to reduce NOx emission. Experimental research is difficult because of the complexity of the chemical reactions related with nitrogen. Based on Miller and Bowman's overall elementary reaction model, NO formation and destruction under fuel staging is calculated in this paper. The accordance of the calculation results with experimental data show that the above model is good for predicting NOx formation and destruction. Sensitivity analysis shows that C, CH, CH2 and HCCO play an important role in NO destruction and reducing under fuel staging. NO generated in the primary zone can be reduced effectively by staged combustion. The main factors that affect NO reducing are the air-fuel ratio in the primary combustion zone, the combustion temperature in the reburning zone and the mass factor of the reburning fuel in the overall fuel. The best air-fuel ratio in the primary combustion zone for NO reducing in the reburning zone is 1. The raising of the temperature in the reburning zone is good for the reducing of NO. The best mass fraction of the reburning fuel in the overall fuel for NO destruction is 30%.
Nitrogen oxides, combustion, fuel staging, modelling
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【期刊论文】Modeling of homogeneous mercury speciation using detailed chemical kinetics
徐明厚, Minghou Xu, a, *, Yu Qiao, Chuguang Zheng, Laicai Li, b, Jing Liu
Combustion and Flame 132(2003)208-218,-0001,():
-1年11月30日
mechanism including Hg reactions involving HgO was proposed. Among those reactions involving HgO, the progress of reaction HgO +HCl→HgCl+OH is HgO+HCl→TS1(HgClOH)→M(HgClOH)→TS2(HgClOH)→HgCl+OH, in which the controlling step is HgO+HCl→TS1(HgClOH)→M(HgClOH). The progress of reaction HgO+HOCl→HgCl+HO2 is HgO+HOCl→M(HgClOOH)→TS(HgClOOH)→HgCl+ HO2, in which the controlling step is M(HgClOOH)→TS(HgClOOH)→HgCl+HO2. Four other reactions are one-step, with no intermediates formed. The performance of the model was assessed through comparisons with experimental data conducted by three different groups. The comparison shows that model calculations were in agreement with only one set of all the three groups experimental data. The deviation occurs due to the absence of accurate rate constants of existing echanism, the adding of reactions involving HgO, as well as the exclusion of heterogeneous Hg oxidation mechanism. Analyses by quantum chemistry and sensitivity simulations illustrated that the pathway Hg+ClO=HgO+Cl is more significant than some of the key reactions in the kinetic mechanism proposed in the literature, which indicates the necessity of including reactions involving HgO in the mercury speciation kinetic mechanism. Studies on the effects of oxygen show that O2 weakly promotes homogeneous Hg oxidation, especially under the condition of low Cl2 concentration. In all cases, 1.5–6.0% of the mercury is predicted to be present as HgO.
Keywords: Mercury speciation, Reaction mechanism, Quantum chemistry, Kinetic modeling
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